Gold and nickel alkyl substituted bis-thiophenedithiolene complexes: anionic and neutral forms

Marta M. Andrade, Rafaela A. L. Silva, Isabel C. Santos, Elsa B. Lopes, Sandra Rabaça, Laura C. J. Pereira, Joana T. Coutinho, João P. Telo, Concepció Rovira, Manuel Almeida and Dulce Belo

Inorg. Chem. Front., 2017,4, 270-280

Abstract

The effect of substituents on the magnetic and transport properties is assessed for Au and Ni alkyl substituted bisthiophenedithiolates.

Synthesis and characterization of a family of thioether-dithiolate-bridged heteronuclear iron complexes

Yahui Zhang, Dawei Yang, Ying Li, Baomin Wang, Xiangyu Zhao and Jingping Qu

Dalton Trans., 2017,46, 7030-7038

Abstract

Five heterotrinuclear complexes and one heterobinuclear complex are successfully synthesized. These complexes are all well characterized by various spectroscopy studies.

Biomimetic catalytic oxidative coupling of thiols using thiolate-bridged dinuclear metal complexes containing iron in water under mild conditions

Yahui Zhang, Dawei Yang, Ying Li, Xiangyu Zhao, Baomin Wang and Jingping Qu

Catal. Sci. Technol., 2019,9, 6492-6502

Abstract

A green approach to disulfides via aerobic oxidative coupling of thiols was developed with a thiolate-bridged heteronuclear complex in water.

^52g/55Mn-Labelled CDTA-based trimeric complexes as novel bimodal PET/MR probes with high relaxivity

Marie R. Brandt, Christian Vanasschen, Johannes Ermert, Heinz H. Coenen and Bernd Neumaier

Dalton Trans., 2019,48, 3003-3008

Abstract

Multimeric trans-1,2-diaminocyclohexane-N,N,N′,N′-tetraacetic acid (CDTA) derivatives labelled with a mixture of paramagnetic ⁵⁵Mn(II) and β⁺-emitting ^52gMn(II) offer the access to bimodal Positron Emission Tomography/Magnetic Resonance (PET/MR) tracers.

Phosphorus–nitrogen compounds. Part 37. Syntheses and structural characterizations, biological activities of mono and bis(4-fluorobenzyl)spirocyclotetraphosphazenes

Gamze Elmas, Aytuğ Okumuş, Pelin Sevinç, Zeynel Kılıç, Leyla Açık, Mustafa Atalan, Mustafa Türk, Gökberk Deniz and Tuncer Hökelek

New J. Chem., 2017,41, 5818-5835

Abstract

The syntheses, spectroscopic and crystallographic properties, in vitro cytotoxic and antimicrobial activities of the cyclotetraphosphazenes were investigated.