Kinetic studies of the reactions of two previously characterized copper(III)-hydroxide complexes with a series of para substituted phenols (XArOH where X = NMe2, OMe, Me, H, Cl, NO2, or CF3) indicate competition between concerted CPET and sequential PT/ET pathways.
The reactivity, energetics and dynamics of the bimolecular reactions between Ar2+ and O2 have been studied using a position sensitive coincidence methodology at a collision energy of 4.4 eV.
Electron-withdrawing groups on phenolate donors enhance polycarbonate production from CO2 and cyclohexene oxide by Co(II) amino-bis(phenolate) complexes.
Carbon nanomaterials have been introduced as a scaffold for various biological applications due to their unique physical and electrical properties.
Dimeric BHT-alkoxy magnesium complexes are able to catalyze ROP of lactones and lactides by the binuclear mechanism.