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Probing the binding modes and dynamics of histidine on fumed silica surfaces by solid-state NMR


Haley L. Swanson, Chengchen Guo, Michael Cao, J. Bennett Addison and Gregory P. Holland
Phys. Chem. Chem. Phys., 2020,22, 20349-20361
From themed collection: 2020 PCCP HOT Articles

Abstract

Silica nanoparticles can be designed to exhibit a diverse range of morphologies (e.g. non-porous, mesoporous), physical properties (e.g. hydrophobic, hydrophilic) and a wide range of chemical and biomolecular surface functionalizations.


Multi-spectroscopic and theoretical analyses on the diphenyl ether–tert-butyl alcohol complex in the electronic ground and electronically excited state


Dominic Bernhard, Fabian Dietrich, Mariyam Fatima, Cristobal Perez, Anja Poblotzki, Georg Jansen, Martin A. Suhm, Melanie Schnell and Markus Gerhards
Phys. Chem. Chem. Phys., 2017,19, 18076-18088

Abstract

Multi-spectroscopic and theoretical investigations on the isolated diphenyl ether–tert-butyl alcohol complex – an ideal benchmark system for theory with strongly competing OH–O and OH–π binding motifs.


Mixed chelating ligands used to regulate the luminescence of Ln(III) complexes and single-ion magnet behavior in Dy-based analogues


Hai-Ling Wang, Xiong-Feng Ma, Hua-Hong Zou, Kai Wang, Bo Li, Zi-Lu Chen and Fu-Pei Liang
Dalton Trans., 2018,47, 15929-15940

Abstract

The organic ligands 5,7-dibromo-2-methyl-8-quinolinol (L1), 1,10-phenanthroline (L2), and 5,7-dichloro-2-methyl-8-quinolinol (L3) were used to react with Dy(NO3)3·6H2O under solvothermal conditions at 80 °C to obtain the complexes [Dy(L1)3(H2O)] (1), [Dy(L2)2(NO3)3] (2), and [Dy(L3)3(H2O)] (3), respectively.


Quadratic nonlinear optical (NLO) properties of borazino (B3N3)-doped nanographenes


Nicolás Otero, Claude Pouchan and Panaghiotis Karamanis
J. Mater. Chem. C, 2017,5, 8273-8287

Abstract

When inorganic benzene is confined in the honeycomb structure of nanographenes, it triggers impressive NLO variations powered by the local electron delocalization effects.


Fundamental scaling laws for the direct-write chemical vapor deposition of nanoscale features: modeling mass transport around a translating nanonozzle


Lee W. Drahushuk, Ananth Govind Rajan and Michael S. Strano
Nanoscale, 2019,11, 2925-2937

Abstract

The nanometer placement of nanomaterials, such as nanoribbons and nanotubes, at a specific pitch and orientation on a surface, remains an unsolved fundamental problem in nanotechnology.


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