Three organic–inorganic hybrid POMs were prepared and characterized, exhibiting 0-D to 2-D assemblies made by {Ni6PW9} SBUs and organic ligands.
Two new hexa-Ni-substituted polyoxometalates are made and characterized, exhibiting electrochemical performance and photocatalytic activity for the degradation of organic dyes under UV irradiation.
Three hexa-Ni-substituted Keggin phosphotungstate chains have been obtained through the SAC method, where H2N-bdc and unprecedented {(Ni6PW9)PW12} is reported for the first time.
Organic–inorganic composites are reported, where 3D printing, chemical surface modification and molecular metal oxide deposition are combined, enabling heavy metal removal from water.
{2}-Metallacryptates are constructed from the self-assembly of 2,6-dipicolinoylbis(N,N-diethylthiourea) ligands and mixtures of indium(III) chloride and chlorides of monovalent cations.