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Stepwise synthesis, characterization, DNA binding properties and cytotoxicity of diruthenium oligopyridine compounds conjugated with peptides


Konstantinos Ypsilantis, John C. Plakatouras, Manolis J. Manos, Andreas Kourtellaris, Georgios Markopoulos, Evangelos Kolettas and Achilleas Garoufis
Dalton Trans., 2018,47, 3549-3567

Abstract

The conjugation of peptides to diruthenium complexes was achieved.


The balance of electric field and interfacial catalysis in promoting water dissociation in bipolar membranes


Zhifei Yan, Liang Zhu, Yuguang C. Li, Ryszard J. Wycisk, Peter N. Pintauro, Michael A. Hickner and Thomas E. Mallouk
Energy Environ. Sci., 2018,11, 2235-2245

Abstract

Bipolar membranes maintain a steady pH in electrolytic cells through water autodissociation at the interface between their cation- and anion-exchange layers. We analyze the balance of electric field and catalysis in accelerating this reaction.


Highly versatile heteroditopic ligand scaffolds for accommodating group 8, 9 & 11 heterobimetallic complexes


Mark R. D. Gatus, Mohan Bhadbhade and Barbara A. Messerle
Dalton Trans., 2017,46, 14406-14419

Abstract

Two highly versatile xanthene scaffolds containing pairs of heteroditopic ligands were found to be capable of accommodating a range of transition metal ions, including Au(I), Ir(I), Ir(III), Rh(I), and Ru(II) to generate an array of heterobimetallic complexes.


Determination of the electronic structure of a dinuclear dysprosium single molecule magnet without symmetry idealization


Mauro Perfetti, Maren Gysler, Yvonne Rechkemmer-Patalen, Peng Zhang, Hatice Taştan, Florian Fischer, Julia Netz, Wolfgang Frey, Lucas W. Zimmermann, Thomas Schleid, Michael Hakl, Milan Orlita, Liviu Ungur, Liviu Chibotaru, Theis Brock-Nannestad, Stergios Piligkos and Joris van Slageren
Chem. Sci., 2019,10, 2101-2110
From themed collection: Most popular 2018-2019 physical and theoretical chemistry articles

Abstract

We present the in-depth determination of the magnetic properties and electronic structure of the luminescent and volatile dysprosium-based single molecule magnet [Dy2(bpm)(fod)6] (Hfod = 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedione, bpm = 2,2-bipyrimidine).


Photoaccelerated energy transfer catalysis of the Suzuki–Miyaura coupling through ligand regulation on Ir(III)–Pd(II) bimetallic complexes


Su-Yang Yao, Man-Li Cao and Xiu-Lian Zhang
RSC Adv., 2020,10, 42874-42882

Abstract

A series bimetallic catalysts were synthesized. Relationship between the structure of catalysts and catalytic reactivities were studied and improvement of the catalytic efficiency for Suzuki–Miyaura coupling was accomplished by regulating their chromophores.


Chapter 8
Applications of Bipolar Membranes for Electrochemical and Photoelectrochemical Water Splitting


David A. Vermaas and Wilson A. Smith
Advances in Photoelectrochemical Water Splitting: Theory, Experiment and Systems Analysis, 2018, 208-238

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