A bis-carbene-stabilized ethynyl radical cation, a purely organic mixed valence compound, is indefinitely air stable.
A metal-free reductive procedure for decyanation of malononitriles and cyanoacetates, using photoactivated organic electron donors, is described.
Three-component reaction of carbodiimides, acyl chlorides, and isocyanides took place smoothly at room temperature to afford 1,4-disubstituted 5-acetamidoimidazoles in good yields.
Species-specific double and triple isotope dilution mass spectrometry (IDMS) was applied for the precise quantification of Cu,Zn-SOD in human erythrocytes.
The synthesis of a full series of group 4/nickel complexes supported by a 2-(diphenylphosphino)pyrrolide (NP) ligand is reported.
Supramolecular assembly of peptide-based monomers into nanostructures offers many promising applications in advanced therapies. In this Tutorial Review, we introduce molecular designs to control the structure and potential biological function of supramolecular assemblies.
An azide derivative of hyperbranched poly(arylene oxindole) is synthesized for postgrafting by CuAAC. RGDS functionalization promotes cell attachment and proliferation.
In this work, we establish an approach for the three-dimensional (3D) culture and differentiation of induced pluripotent stem cells (iPSCs) within well-defined synthetic matrices using light-based chemistries of relevance for the study of both disease and regeneration.
Solvent-cast 3D printing with peptide–polymer conjugates introduces a versatile platform to spatially organize peptides to guide local cell behavior.
Using photoresponsive host–guest chemistry, three different payloads can be photo-released successively from the same peptide hydrogel.