Supported Catalysts and Their Applications

The need to improve both the efficiency and environmental acceptability of industrial processes is driving the development of heterogeneous catalysts across the chemical industry, including commodity, specialty and fine chemicals and in pharmaceuticals and agrochemicals. Drawing on international research, Supported Catalysts and their Applications discusses aspects of the design, synthesis and application of solid supported reagents and catalysts, including supported reagents for multi-step organic synthesis; selectivity in oxidation catalysis; mesoporous molecular sieve catalysts; and the use of Zeolite Beta in organic reactions. In addition, the two discrete areas of heterogeneous catalysis (inorganic oxide materials and polymer-based catalysts) that were developing in parallel are now shown to be converging, which will be of great benefit to the whole field. Providing a snapshot of the state-of-the-art in this fast-moving field, this book will be welcomed by industrialists and researchers, particularly in the agrochemicals and pharmaceuticals industries.

From the book series:
Special Publications

Supported Catalysts and Their Applications Editors: David C Sherrington, A P Kybett

Front cover

Front matter

Preface

Contents

Selectivity in oxidation catalysis

The development and application of supported reagents for multi-step organic synthesis

Mesoporous molecular sieve catalysis: Relationships between reactivity and long range structural order/disorder

Zeolite beta and its uses in organic reactions

Chiral mesoporous hybrid organic-inorganic materials in enantioselective catalysis

Immobilised lewis acids and their use in organic chemistry

Influence of zeolite composition on catalytic activity

Synthesis of soluble libraries of macrocycles from polymers: Investigations of some possible screening methods using polymers

Immobilised catalysts and their use in the synthesis of fine and intermediate chemicals

Catalytic aziridination and epoxidation of alkenes using modified microporous and mesoporous materials

Enantioselective alkylation of benzaldehyde by diethylzinc with (-)-ephedrine supported on MTS. A new class of more efficient catalysts

Supported perfluoroalkanedisulphonic acids as catalysts in isobutane alkylation

Polymer immobilised TEMPO (PIPO): An efficient catalytic system for environmentally benign oxidation of alcohols

The preparation and functionalisation of (vinyl)polystyrene polyhipe. Short routes to binding functional groups through a dimethylene spacer

Polynitrogen strong bases as immobilized catalysts

Selective synthesis of 2-acetyl-6-methoxynaphthalene over hbea zeolite

The influence of „superacidic“ modification on ZrO2 and Fe2O3 catalysts for methane combustion

Structure and reactivity of polymer-supported carbonylation catalysts

An original behaviour of copper(II)-exchanged Y faujasite in the ruff oxidative degradation of calcium gluconate

Polymer-bound organometallic complexes as catalysts for use in organic synthesis

Dehydroisomerisation of n-butane into isobutene over ga-containing zeolite catalysts

Guanidine catalysts supported on silica and micelle templated silicas. New basic catalysts for organic chemistry

Organic modification of hexagonal mesoporous silica

Towards phthalocyanine network polymers for heterogeneous catalysis

Suzuki coupling using Pd(0) and KF/Al2O3

Unusual regioselectivities observed in the oligomerization of propene on nickel(II) ion-exchanged silica-alumina catalysts

Selectivity through the use of heterogeneous catalysts

Novel lewis-acidic catalysts by immobilisation of ionic liquids

Heterogeneous enantioselective hydrogenation of trifluoro-methyl ketones

Structural and reactive properties of supported transition metal triflates

Soluble fluoropolymer catalysts for hydroformylation of olefins in fluorous phases and supercritical CO2

Subject index

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