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Nitroxides: Synthesis, Properties and Applications Editors: Olivier Ouari, Didier Gigmes

About this book

Nitroxides are versatile small organic molecules possessing a stabilised free radical. With their unpaired electron spin they display a unique reactivity towards various environmental factors, enabling a diverse range of applications. They have uses as synthetic tools, such as catalysts or building blocks; imaging agents and probes in biomedicine and materials science; for medicinal antioxidant applications; and in energy storage. Polynitroxides (polymers bearing pendant nitroxide sidechains) have been used in organic radical batteries, oxidation catalysts and in exchange reactions for constructing complex architectures. Chapters in this book cover the synthesis of nitroxides, EPR studies and magnetic resonance applications, physiochemical studies, and applications including in batteries, imaging and organic synthesis. With contributions from leaders in the field, Nitroxides will be of interest to graduate students and researchers across chemistry, physics, biology and materials science.

Book content

  • Introduction, Evolution and Outlook
  • General Approaches to Synthesis of Nitroxides
  • The Application of Nitroxides in Organic Synthesis
  • Sprin Probes and Imaging Using Nitroxides
  • Nitroxides in Battery-related Applications
  • Computational Tools for Nitroxide Design
  • Nitroxide Mediated Polymerisation
  • Nitroxides in Supramolecular Chemistry
  • Magnetism of Nitroxides
  • Applications of Nitroxide Spin Labels to Structural Biology
  • Nitroxides in Liquid Crystals
  • Nitroxide Intervention in Oxidative and Free Radical Damage in Biology and Disease
  • Spring Trapping
  • Nitroxides as Redox Probes for Preclinical Imaging
  • Introduction to Electron Paramagnetic Resonance

The print version of this book is planned for release on 14 May 2021. Information about this book is subject to change without notice.

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This book contains 592 pages.

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