This chapter presents a summary of manuscripts published in the period of June 2012–June 2013 involving NMR techniques and their applications in the field of amphiphilic systems. In Section 2 reviews and articles on general methods and models have been considered. In Section 3 the manuscripts on thermotropic and lyotropic liquid crystals, phospholipids, vesicles and bicelles have been presented. Section 4 has been devoted to micellar solutions including ionic and non ionic surfactant systems, polymer amphiphiles and mixed amphiphiles systems.