A normally-off hydrogen-terminated diamond phototransistor with high responsivity and rejection ratio

Abstract

Phototransistors possess superior detection capabilities, including high responsivity, large light-to-dark current ratio, and flexible gate controllability, making them attractive for diamond-based solar-blind photodetection. This work presents a hydrogen-terminated diamond (H-diamond) phototransistor with a metal-semiconductor field-effect transistor (MESFET) structure. The dark current of the H-diamond phototransistor was suppressed down to an extremely low magnitude of 10 - 14 A under positive gate voltage (VGS). Under 222 nm UV illumination, it achieves a remarkable responsivity (Rλ) of 1.42 × 10 7A/W at negative VGS. The spectral rejection ratios at positive VGS reach 5.13 × 10 8 and 2.11 × 10 7 for R222nm/R365nm and R222nm/R275nm, respectively, demonstrating good wavelength selectivity. The persistent photoconductivity (PPC) effect also reveals good charge retention of the phototransistor. These findings established a novel pathway for diamond device engineering in solar-blind ultraviolet detection through optimized MESFET configuration design.

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Article information

Article type
Paper
Submitted
06 Feb 2026
Accepted
14 May 2026
First published
29 May 2026

J. Mater. Chem. C, 2026, Accepted Manuscript

A normally-off hydrogen-terminated diamond phototransistor with high responsivity and rejection ratio

Z. Jia, M. Qiu, M. Jiang, J. Cai, X. Chen, Y. Shen, M. Yang, K. Nishimura, W.A. C. Kuan, N. Jiang, H. Li, B. Wang and Q. Yuan, J. Mater. Chem. C, 2026, Accepted Manuscript , DOI: 10.1039/D6TC00399K

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