Fe3C/Fe Nanoparticles Embedded in N-Doped Carbon as Catalysts for Electrocatalytic Nitrogen Reduction to Ammonia

Abstract

The electrocatalytic nitrogen reduction reaction (NRR) offers a sustainable route for ammonia synthesis but is severely hindered by the inertness of N₂, its low solubility, and the competing hydrogen evolution reaction (HER). To address this trilemma, we design a heterostructure catalyst comprising Fe₃C/Fe nanoparticles embedded within a nitrogen-doped carbon matrix (Fe₃C/Fe@NC). In KOH electrolyte, this catalyst achieves a high NH₃ yield of 8.0 μg h⁻¹ mg cat ⁻¹ and a Faradaic efficiency of 8.7%, and good long-term stability. The performance enhancement arises from a synergistic design. The nitrogen-doped carbon ensures high conductivity and mass transport, while the strong interfacial electronic coupling within the Fe₃C/Fe heterostructure simultaneously strengthens N₂ chemisorption, lowers the energy barrier for the rate-determining step (RDS), and optimizes hydrogen adsorption to effectively suppress HER. This work provides a robust and rational heterostructure engineering strategy for advancing ambient NRR electrocatalysis.