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An electrochemical radical reaction between cyclic 1,3-dicarbonyls and alkenes is reported herein to give di- and tricyclic dihydrofuran derivatives. This methodolgy proceeds via a direct oxidative addition/cyclization sequence without the requirement of catalyst or exogeneous oxidant, and with hydrogen as the sole by-product.
O. Montiège, E. Zuo, J. Brière and H. Beucher, Org. Biomol. Chem., 2026, Accepted Manuscript , DOI: 10.1039/D6OB00755D
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