Hierarchical strengthening and toughening design of superalloy joints via a chemically complex intermetallic alloy-modified diffusion bonding strategy

Abstract

Design and fabricating advanced interlayer materials are pivotal for the diffusion bonding (DB) of precision and slip-structure turbine components in aero-engines. Here, we developed a chemically complex intermetallic alloy (CCIMA) interlayer exhibiting exceptional mechanical properties at both room and elevated temperatures. Acting as the core of a tailored "BNi-2/CCIMA/BNi-2" sandwich interlayer, the CCIMA plays a critical role for joining powder metallurgy superalloys via the multi-interlayer composite bonding (MICB) strategy. This innovative approach leads to the formation of a robust hetero-structured joint architecture comprising alternating diffusion-affected zones (DAZs), isothermally solidified zones (ISZs), and a central CCIMA region. The CCIMA core, featuring recrystallized L1 2 -ordered grains, critically promotes the extensive precipitation of cuboidal L1 2 nanoparticles within the ISZs.At the optimized bonding condition (1150 °C, 2 h), detrimental Nb-Ta-rich borides in the CCIMA region are completely suppressed, while a high-density (~57 vol. %, ~367 nm diameter) of L1₂ precipitates forms in the ISZ. The resulting joints achieve an ultimate tensile strength of ~1325.7 MPa (> 93% of the base metal (BM) strength) and elongation of ~27.7%, which is comparable to the BM's ductility. This outstanding performance is attributed to hierarchical strengthening and toughening mechanisms induced by the CCIMA interlayer, including macroscale strain delocalization enabled by the hetero-structured architecture, microscale dislocation pinning via grain boundaries/serrated bonded interfaces and L1 2 precipitates, and atomic-level bonding enhancement through tailored diffusion control. This work highlights the critical role of CCIMA as a functional interlayer material, establishing a new paradigm for manufacturing/repairing high-performance turbine components in next-generation aeroengines.