A new mixed alkali tin sulfate fluoride birefringent crystal Na2SnSO4F2 was successfully synthesized and grown. It exhibits a large birefringence of 0.086 at 1064 nm and matain a large bandgap. Theoretical calculations indicate that the relatively well-aligned of [SnOF2] polyhedra are the primary contributor to the large birefringence.
J. Wang, W. Zhang, X. Ma, F. Zhang, H. Du and S. Han, Dalton Trans., 2026, Accepted Manuscript , DOI: 10.1039/D5DT02815A
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