Breaking the Boltzmann Limit in Sub-5-nm Monolayer CdPS 3 Transistors

Abstract

Tunnel field-effect transistors (TFETs) have gained considerable attention for their potential to overcome the 60 mV/dec Boltzmann limit of conventional metal-oxide-semiconductor field-effect transistors (MOSFETs). Using first-principle quantum transport simulations, we investigate the suitability of monolayer CdPS3 (ML CdPS3) for sub-5 nm logic devices and examine its anisotropic properties. Our results show that ML CdPS3 MOSFETs oriented along the zigzag direction exhibit pronounced tunneling-dominated transport, achieving an ultrasteep minimum subthreshold swing (SS) of 37.8 mV/dec. This characteristic enables devices with a 3-nm gate length to meet the high-performance standards set by the International Roadmap for Devices and Systems (IRDS). Leveraging its unique quantum transport properties, ML CdPS3 emerges as a strong candidate for next-generation high-performance nanoelectronics.

Supplementary files

Article information

Article type
Paper
Submitted
28 Feb 2026
Accepted
20 Apr 2026
First published
22 Apr 2026

Phys. Chem. Chem. Phys., 2026, Accepted Manuscript

Breaking the Boltzmann Limit in Sub-5-nm Monolayer CdPS 3 Transistors

M. Wang and Y. Mao, Phys. Chem. Chem. Phys., 2026, Accepted Manuscript , DOI: 10.1039/D6CP00753H

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