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We report a practical photocatalytic strategy for alkene difunctionalization by reaction with benzoyl cyanides and boronic acids, efficiently affording α-branched aryl ketones. This method features broad substrate scope, excellent functional group tolerance, and enables quaternary carbon construction, product post-modification, and acylarylation of Estrone and Clofibrate.
Z. Xi, Z. Dong, Z. Ji, K. Zhang, F. Zhao, Q. Yuan and Y. Shen, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC02335E
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