The maximum methanol selectivity in plasma driven methane oxidation at a specific reduced electric field (E/N) arises from kinetic competition between the CH3O + H + M and CH3OH + O pathways. Tuning E/N to balance these competing rates achieves high selectivity, providing a principle for process design.
L. Wang, P. Du, Y. Song, Z. Lou, Z. Xie and Z. Zhao, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC01974A
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