We report a two-molecule photoredox system enabling deoxygenative radical addition of aryl carboxylic acids to electrondeficient alkenes under mild conditions. Cooperative action of an organic photocatalyst and a phosphine facilitates acyl radical generation and efficient carbon-carbon bond formation without metal reagents.
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N. Maruyama, Y. Kawabata, N. Kinoshita, T. Furutani, C. Sakamoto, Y. Yoshimi and M. Yamawaki, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC00700G
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