The number of Co-nitrosyls having {Co(NO)} 8 configuration, which donate HNO under specific reaction conditions, is only a handful. A Co-nitrosyl complex, [Co(TMTAA 2 ˉ)(NO)], 1a [TMTAA 2 ˉ = 5,7,12,14tetramethyldibenzotetraaza[14]annulene dianion] of {Co(NO)} 8 configuration is shown to donate NOˉ in the presence of imidazole.
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B. Mondal, B. M. Deka, S. Saha and A. K. Guha, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D6CC00661B
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