We propose 1,3-dimethyl-2-imidazolidinone (DMI) as a novel electrolyte additive. It enhances cycling stability (105.5 mAh g-1 after 200 cycles) and rate capability (99.7 mAh g-1 after 450 cycles at 5C) in Na3V2(PO4)3 (NVP) cathodes. DMI preferentially oxidizes to form a protective cathode film, as confirmed by combined analyses.
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Q. Lin, X. Cai, W. Han, Y. Zhang, L. Zhang, Z. Zhou and L. Fan, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D5CC07224G
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