The straightforward synthesis of the first difluoro dipyridomethene boron complexes as heavy-atom-free photosensitizers is described. These molecules show good singlet oxygen generation (ϕΔ = 10 to 47%) and significant nonplanar arrangement, inducing axial and boron-centered chirality.
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C. Figliola, C. Chériaux, N. Oppé, L. Estaque, P. Retailleau, N. Vanthuyne, G. Pieters, D. Jacquemin and G. Ulrich, Chem. Commun., 2026, Advance Article , DOI: 10.1039/D5CC06879G
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