We demonstrate reversible redox chemistry for protonated pyridyl disulfide/thiol (Dp-PySSPy/p-PySH) in aqueous organic flow batteries (AOFBs). The lightest hydrophilic group (H+) endows Dp-PySSPy with super hydrophilicity, thus leading to a high volumetric capacity of 90.0 Ah L-1. This work broadens the family of organic redox-active materials for designing AOFBs.
Q. Chen, W. Guo and Y. Fu, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D5CC06626C
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