The reactive metal–support interaction (RMSI) between Ag and defective TiOx spontaneously triggers the selective silver-catalyzed hydrogenation of dimethyl oxalate to methyl glycolate, enabling a >5-fold increase in TOF without prereduction. Importantly, TiOx confers remarkable oxidation resistance to the metallic Ag phase.
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X. Duan, W. Zhao, Z. Chen, J. Zheng, H. Lin, L. Ye and Y. Yuan, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D5CC06528C
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