A divergent approach was developed towards the synthetic studies of bisabosqual A and fargenone B for the first time. The key oxygenated five or seven-membered ring in [6-5-6] and [6-7-6] tricyclic core of these two natural products could be constructed through a regioselective intramolecular SN2 reaction from the common advanced intermediate 11.
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C. Guo, M. Zhu, S. Ze Lang, Y. Wang, J. Xiao and Y. Peng, Org. Biomol. Chem., 2025, Accepted Manuscript , DOI: 10.1039/D5OB00655D
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