Self-recoverable broadband near infrared mechanoluminescence from BaGa12O19:Cr3+ by multi-site occupation strategy

Abstract

Near infrared mechanoluminescence (NIR-ML) materials have attracted the attention of researchers due to their unique advantages, such as high resistance to bright-field interference and higher penetration depth into biological tissues. However, the reported NIR-ML materials are mainly focused on rare ion activated narrow-band emission ones. In this work, we report a NIR-ML material of BaGa12O19:Cr3+ by solid state rection method. The bright broad NIR ML (650-1000 nm) is observed at lower force loads (12N), which is based on the Cr3+ ion’s multi-lattice site occupation. After heat treatment at 573 K for 20 min, BaGa12O19:Cr3+ still maintains 84.4% of its ML intensity. Furthermore, the ML intensity of BaGa12O19:Cr3+ is also significantly improved after UV pre-irradiation. Due to the defective piezoelectric photonic effect, BaGa12O19:Cr3+ has great self-recoverable properties even in the absence of UV and sunlight irradiation. Finally, the ML penetration rate of BaGa12O19:Cr3+ has reached as high as 66.97% in biological tissues, which suggests a potential prospect for biostress detection towards bio-imaging applications.