SCHEDULED MAINTENANCE:
A tetraphenylethylene (TPE)-functionalized diacetylene monomer undergoes direct violet-phase polydiacetylene (PDA) under 254 nm UV, bypassing conventional blue-phase formation. Steric constraints from the bulky TPE units force backbone distortion. The resulting polydiacetylene exhibits reversible violet-to-red thermochromism at 69°C with reversible thermochromism.
To support increased transparency, we offer authors the option to publish the peer review history alongside their article.
C. Zhang and C. He, Phys. Chem. Chem. Phys., 2025, Accepted Manuscript , DOI: 10.1039/D5CP02612A
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
