Symmetry breaking is difficult to achieve in achiral systems as nonselective supramolecular self-assembly typically results in racemic mixtures. Here, we reported a novel finding of spontaneous supramolecular chiral formation in achiral poly(3-alkylthiophene) (P3AT). Our results establish a valid approach for generating circularly polarized luminescence (CPL) properties from achiral polymers.
K. Jiang, L. Chen, Y. Liang and B. Duan, Chem. Commun., 2025, Accepted Manuscript , DOI: 10.1039/D5CC04914H
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