We report the synthesis and structural characterization of PtAg4Cl(BDPP)4H]2+, a novel bimetallic complex featuring an intrinsically chiral architecture. The heterometallic Pt–Ag core exhibits distinctive optical properties, while the chiral BDPP (BDPP is 2,4-bis(diphenylphosphino)pentane) ligand not only induces structural asymmetry but also fine-tunes the electronic and steric characteristics of the complex.
Y. Zhang, H. Jia, B. Yan, J. Hou, H. Guo, Q. Li, C. Xin, S. Li, J. Dong and H. Shen, Chem. Commun., 2025, Accepted Manuscript , DOI: 10.1039/D5CC03572D
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