Two pyrene-based cagearene constitutional isomers: synthesis, separation, and host–guest chemistry

Yating Li; Shang Li; Mengbin Wang; Li Shao; Shuai Fang; Bin Hua; Feihe Huang

doi:10.1039/D4QO01142B

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Two pyrene-based cagearene constitutional isomers: synthesis, separation, and host–guest chemistry†

Yating Li,‡^a Shang Li,‡^a Mengbin Wang,^b Li Shao,

^c Shuai Fang,*^a Bin Hua

*^ab and Feihe Huang

*^ab

Author affiliations

* Corresponding authors

^a Stoddart Institute of Molecular Science, Department of Chemistry, Zhejiang University, Hangzhou 310058, P. R. China
E-mail: fangshuai123@zju.edu.cn, huabin@zju.edu.cn, fhuang@zju.edu.cn
Fax: +86-571-8795-3189
Tel: +86-571-8795-3189

^b Zhejiang-Israel Joint Laboratory of Self-Assembling Functional Materials, ZJU-Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311215, P. R. China

^c Department of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, P. R. China

Abstract

Herein we successfully synthesize two pyrene-based cagearene constitutional isomers and achieve their separation based on their different crystallization rates. Moreover, the optical properties and host–guest chemistry of these two isomers are investigated.

This article is part of the themed collection: Celebrating the 60th birthday of Professor Frank Würthner

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DOI: https://doi.org/10.1039/D4QO01142B
Article type: Research Article
Submitted: 22 Jun 2024
Accepted: 18 Jul 2024
First published: 19 Jul 2024

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Org. Chem. Front., 2024, Advance Article

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Two pyrene-based cagearene constitutional isomers: synthesis, separation, and host–guest chemistry

Y. Li, S. Li, M. Wang, L. Shao, S. Fang, B. Hua and F. Huang, Org. Chem. Front., 2024, Advance Article , DOI: 10.1039/D4QO01142B

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Two pyrene-based cagearene constitutional isomers: synthesis, separation, and host–guest chemistry†

Abstract

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Two pyrene-based cagearene constitutional isomers: synthesis, separation, and host–guest chemistry

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