Reactive collisions between electrons and BeH+ above dissociation threshold

Abstract

Our previous studies of dissociative recombination and vibrational excitation/de-excitation of the BeH+ ion, based on the multichannel quantum defect theory, are extended to collision energies above the dissociation threshold, taking into account the vibrational continua of the BeH+ ion and, consequently, its dissociative excitation. We have also significantly increased the number of dissociative states of 2Π, 2Σ+ and 2Δ symmetry included in our cross section calculations, generating the most excited ones by using appropriate scaling laws. Our results are suitable for modeling the kinetics of BeH+ in edge fusion plasmas for collision energies up to 12 eV.

Graphical abstract: Reactive collisions between electrons and BeH+ above dissociation threshold

Article information

Article type
Paper
Submitted
26 Apr 2024
Accepted
28 May 2024
First published
03 Jun 2024

Phys. Chem. Chem. Phys., 2024, Advance Article

Reactive collisions between electrons and BeH+ above dissociation threshold

E. Djuissi, J. Boffelli, R. Hassaine, N. Pop, V. Laporta, K. Chakrabarti, M. Ayouz, A. Bultel, J. Z. Mezei and I. F. Schneider, Phys. Chem. Chem. Phys., 2024, Advance Article , DOI: 10.1039/D4CP01736F

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