A neutral Mn(II)-BIF for electrocatalytic oxygen reduction reaction

Minhong Li; Jingran Zhong; Chengjie Liao; Wenjuan Fan; Jin Lu; Dexiang Zhang; Tian Wen; Zhiqiang Jiang

doi:10.1039/D5DT01965F

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A neutral Mn(ii)-BIF for electrocatalytic oxygen reduction reaction

Minhong Li,

^a Jingran Zhong,^a Chengjie Liao,^a Wenjuan Fan,^a Jin Lu,^a Dexiang Zhang,^a Tian Wen

*^ab and Zhiqiang Jiang*^a

Author affiliations

* Corresponding authors

^a Vanadium and Titanium Critical Strategic Materials Key Laboratory of Sichuan Province, School of Vanadium and Titanium, Panzhihua University, Sichuan, P. R. China
E-mail: jiangzq@pzhu.edu.cn, wentian@pzhu.edu.cn

^b School of Chemistry, Monash University, Clayton, VIC 3800, Australia

Abstract

A neutral Mn(II) boron imidazolate framework (BIF-251) containing an unexpected bridging formate linker was synthesized in situ via a solvothermal reaction without directly using formic acid. This newly developed Mn-BIF ORR electrocatalyst offers valuable insights into the design of Mn-based BIF materials for renewable energy applications.

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Article information

DOI: https://doi.org/10.1039/D5DT01965F
Article type: Communication
Submitted: 18 Aug 2025
Accepted: 21 Oct 2025
First published: 22 Oct 2025

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Dalton Trans., 2025,54, 17414-17417

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A neutral Mn(II)-BIF for electrocatalytic oxygen reduction reaction

M. Li, J. Zhong, C. Liao, W. Fan, J. Lu, D. Zhang, T. Wen and Z. Jiang, Dalton Trans., 2025, 54, 17414 DOI: 10.1039/D5DT01965F

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Dalton Transactions

A neutral Mn(ii)-BIF for electrocatalytic oxygen reduction reaction

Abstract

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A neutral Mn(II)-BIF for electrocatalytic oxygen reduction reaction

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