Progress in phenanthroline-derived extractants for trivalent actinides and lanthanides separation: where to next?

Abstract

Spent nuclear fuel (SNF) released from reactors possesses significant radioactivity, heat release properties, and high-value radioactive nuclides. Therefore, using chemical methods for reprocessing can enhance nuclear energy's economic efficiency and reduce potential environmental risks. Due to the presence of relatively diffuse f-electrons, the chemical properties of trivalent lanthanides (Ln(III)) and actinides (An(III)) in SNF solutions are quite similar. Separation methods have several limitations, including poor separation efficiency and the need for multiple stripping agents. The use of novel multi-dental phenanthroline-derived extractants with nitrogen donor atoms to effectively separate An(III) over Ln(III) has been widely accepted. This review first introduces the development history of phenanthroline-derived extractants for extraction and complexation with An(III) over Ln(III). Then, based on structural differences, those extractants are classified into four categories: nitrogen-coordinated, N,O-hybrid coordinated, highly preorganized structure, and unsymmetric structure. Each category's design principles, extraction, and separation performance as well as their advantages and disadvantages are discussed. Finally, we have summarized and compared the unique characteristics of the existing extractants, and provide an outlook. This work may offer a reliable reference for the precise identification and selective separation between An(III) and Ln(III), and point the way for future development and exploration.