Decarbonising electrical grids using photovoltaics with enhanced capacity factors

.


Introduction
Commercial Photovoltaic (PV) technology based on silicon is technologically mature, deployable at scale, 1,2 and currently one of the cheapest renewable sources of energy. 35][6] However, the shift from dispatchable (i.e. can be turned on as needed) to variable renewable generation including significant contributions from PV creates a range of challenges.From a carbon perspective, time-resolved PV generation does not match demand in many areas of the world, which in turn may necessitate the use of dispatchable fuels like gas, coal, biomass, hydrogen or synthetic fuels to meet the shortfall.Variable renewable generation also creates difficulties for electricity system operators (ESOs), which must meet demand near instantaneously whilst maintaining the supplied voltage and frequency within certain limits, i.e. provide a defined ''power quality''.For example, in some markets such as California, maintaining power quality is a particular challenge around sunset when generation swings from Solar PV to dispatchable sources rapidly over a short space of time, and the magnitude of this swing increases with Solar PV penetration (the so-called ''Duck Curve'' effect 7 ).Power quality is also an issue for low voltage networks, such as those on which most rooftop solar panels are connected, since reverse power flow during sunny periods can lead to overvoltage. 8,9Commercial PV also faces financial challenges as it is predicted that revenues will reduce as PV penetration increases, [10][11][12] though it is noted this may not be true for all energy markets.This value deflation has led some to advocate for more ambitious cost targets for silicon PV to ensure they remain cost competitive. 12All these issues have their root in the relative lack of control as to when PV generates power and are expected to become more serious as the penetration of PV increases.It is expected that grid-level energy storage 13 and demand-side management 14 will play a key role in mitigating these challenges, however, the roll-out of these technologies is arguably not keeping pace with the installation of Solar PV.This motivates the question: can the variability in PV generation itself be minimised?
In the electrical power industry, variability of renewable generation is quantified by the capacity factor, which is the ratio of the actual energy output to the theoretical maximum energy output over a set period.Capacity factors for commercial silicon PVs vary with the local climate, for example, ranging from 10% in the UK 15 to over 25% in California. 16Generally, the capacity factors offered by silicon PV do not compare favourably with other forms of energy generation, for example, the UK's National Statistics Agency estimated in 2021 15 that Offshore wind had a capacity factor of 38%, whilst Biomass had 64%, and Nuclear had 59% (though we note that this is a low value for Nuclear from a historical perspective).Maximising capacity factor through generator design is a recognised approach in the wind power sector 17 to address the challenges of variable generation listed above. 18However, at present, the techniques to increase capacity factor in solar PV are limited and external to the solar cell itself, such as installation of east/ west facing panels to extend generation into the morning and evening, 19,20 or the use of tracking mounts. 21,22n this paper we demonstrate a class of PV devices that have intrinsically higher capacity factor than conventional PV technology.These devices, which we term High Capacity Factor Photovoltaics, or CFPV, have a power conversion efficiency (PCE) which increases as irradiance reduces.This behaviour boosts generation at times of low irradiance to both minimise variability in power output and maximise power harvested for a given capacity of grid connection.The benefits that CFPV devices offer for matching supply and demand are demonstrated using a model of the mainland UK energy network.In this context, it is shown that CFPV generation matches demand more effectively than an equivalent capacity of silicon PV, and that this leads to two key benefits that increase with capacity factor: (i) a reduced need for high carbon intensity generation from coal or gas, and (ii) increased income from wholesale markets.CFPV devices based on a dye-sensitised architecture are demonstrated, showing that the capacity factor can be controlled through rational design.Further, the improvement in capacity factor through device design is predicted to be larger than available with external methods, such as singleand dual-axis tracking.Introducing control of the generation profile of Solar PV in this way is expected to reduce the need for, and costs associated with, energy storage and demand-side management elsewhere in the wider energy system.

Results and discussion
Our approach in this work was to use energy systems modelling to establish the benefits of CFPV devices on national carbon emissions and income generation, and demonstrate that CFPV behaviour can be designed rationally through PV device structure.In other words, we aimed to demonstrate both a 'demand pull' (i.e.benefits of CFPV) and a 'technology push' (i.e.ability to design CFPV behaviour) to motivate future work in this area.This paper is organised to discuss the benefits of CFPV at the grid scale first, before moving on to report results from designed CFPV devices.

Modelling CFPV generation at the national scale
To establish the benefits of CFPV, we required both a model of a CFPV device and of an energy network.Considering first the model of the CFPV device, it has been shown that Organic, [23][24][25][26][27] Perovskite [28][29][30][31] and Dye-Cell 32,33 PV architectures can have increasing PCE with reducing light intensity, which may in turn give rise to CFPV behaviour.We selected from these papers [23][24][25][26][27][28][29][30][31][32][33] the data reported by Bristow and Kettle 33 shown in Fig. 1, for a commercial (SolarPrint, Dublin), large-area (5 Â 5 cm) dye-sensitised PV module measured in an outdoor test (Bangor, Wales).Here slow ion transportation in the electrolyte led to limited mass transport under high irradiance and lower PCE.Thus, lowering irradiance from 1000 Wm À2 reduced the required transportation rate and increased the PCE.We stress that our selection of the devices from Bristow and Kettle 33 was due to the measurements being taken outdoors on a large-area PV device to provide a realistic test Fig. 1 PCE irradiance characteristics of CFPV devices as reported by 33 (line), and those devices reported here (symbols) with t TiO 2 = 12 (pentagons), 18 (squares), 24 (triangles) and 48 mm (circles).

Paper
Energy & Environmental Science View Article Online of the CFPV concept.Other PVs based on Perovskite [28][29][30][31] or Organic [23][24][25][26][27] absorbers have also been shown to achieve CFPV behaviour as well as different PCE under AM1.5 conditions.The opportunities this raises for future CFPV technologies will be discussed in the context of the results later in the paper.

View Article Online
To quantify how the behaviour shown in Fig. 1 may impact national generation profiles and consequent carbon emissions, a plant dispatch model of the mainland UK electrical network (inc.England, Wales, and Scotland) was developed to predict and compare carbon savings that result from adding varying amounts of CFPV or silicon PV.][36] The UK receives lower irradiance than many countries in the world due to its northerly latitude, however, we stress that increasing the capacity factor of solar PV also has value in sunnier locations.For example, tracking improves capacity factor, and in 2021 more than 85% of US deployed utility scale solar PV capacity (i.e.solar farms of more than 5 MW) incorporated some aspect of tracking. 37These tracking systems were installed in high-irradiance states such as California, Arizona and Texas, as well as less sunny mid-western states, showing there is an economic advantage in increasing capacity factor in both low-and high-irradiance locations.
With the location selected, energy supply within the plant dispatch model was divided into differing dispatch classes (DCs), which represent technologies that are similar in terms of their ability to be curtailed and carbon intensity.These are: DC1, which includes nuclear; DC2 which includes hydrogeneration, curtailable utility scale PV and Wind; DC3 which represents energy storage; whilst DC4 is carbon-intensive gas and coal.The capacities of each DC are listed in ESI † Table S1.Time-resolved energy demand for the year 2016 was assumed to be the sum of dispatched energy for each half-hourly time period, 11 and this demand was met within the model with energy from increasing dispatch classes within each time window, whilst integrating the associated carbon intensity.A flow chart of the dispatch process is shown in ESI † Fig. S1, and a table of the carbon intensity for varying forms of generation is shown in ESI † Table S1.The plant dispatch model was modified from that of Crossland et al. 12 to incorporate PV generation with arbitrary PCE-irradiance characteristics.A detailed description of the calculations and the use of these data is included in ESI † Section S2, but is summarized briefly here.PV generation in DC2 was modelled at a half-hourly resolution using insolation and generation data from the photovoltaic geographical information system 38 (PVGIS) and balancing mechanism reporting service 39 (BMRS).The power generation capability of silicon PVs in the model is based on real historical data, thus we did not specify a PCE-irradiance characteristic.Conversely, for CFPV, we scaled the generation for silicon PV in each time window by an enhancement factor, E derived from the measured PCE irradiance characteristics for CFPV devices: where l is the irradiance in the specified time window, and PCE(1000) is the PCE measured at 1000 Wm À2 .This approach ignores differences in temperature coefficients between silicon PV and CFPV devices.We highlight that the data related to UK energy mix (e.g.Fig. 2) will be reported in terms of energy dispatched, i.e.where the energy was drawn from when it was used to satisfy demand, as opposed energy generated.In most cases, energy generated was dispatched immediately (ESI † Table S1 and Fig. 2a-c), in which case dispatch and generation are synonymous.However, excess generation can also be used to charge energy storage that can be used later, decoupling when energy is generated and when it is dispatched.As an illustrative example, excess solar generation which charges storage which is later dispatched to satisfy demand would be counted as coming from storage rather than solar.Counting energy in this way enabled us to examine how changes in generation alters the usage of energy storage.Fig. S1 of the ESI † describes the process of charging storage in more detail.
We took as our reference the mainland UK electrical grid with associated generation and storage assets in the year 2016, which included 11 970 MW P installed PV that was dominated by silicon, and added to this an additional capacity of silicon PVs (C Si ) or CFPVs (C CF ).The values of C reported here are expressed as a fraction of installed UK PV capacity in 2016 (11 970 MW P ) which defined the power generating capability when irradiance was 1000 Wm À2 .Thus, a simulation for C CF = 0.5 assumes an additional capacity of CFPV assets equal to 50% of the UK PV capacity in DC2 in 2016.We frame our discussion in terms of installed capacity as it is this quantity that significantly affects connections of renewable energy to the grid, including procedure, duration and cost of grid connections. 40In other words, the substations and wires where the solar farm connects to the wider network have a defined capacity, meaning that the solar farm must operate safely on the network without causing any other issues, such as reduced power quality and loss of network protection. 40Further detail as to how the network limits the scope of distributed generation in the UK context is available from the Energy Networks Association in both summary 41 and detailed form. 42

Benefits of CFPV behaviour on national carbon emissions
The CFPV behaviour shown in Fig. 1 was input to the plant dispatch model.Our discussion initially focuses on comparing model predictions for conventional silicon PV and the CFPV devices reported by Bristow and Kettle. 33Fig. 2a and c show the predicted annual UK mix of dispatched energy as a function of additional PV capacity for silicon PV and CFPV devices respectively.Fig. 2d and f shows the same information in as Fig. 2a  and c respectively, but expressed as a change in annual dispatched energy.For both silicon and CFPV, additional generation from solar reduced the need for carbon intensive generation from coal and gas, as well as improving the utilisation of hydropower due to the increased opportunity to 'charge' reservoirs during periods of energy surplus.More importantly, these data show that CFPV devices are more effective per installed capacity at reducing fossil fuel usage than silicon PV.

Paper Energy & Environmental Science
This effectiveness in decarbonization can be quantified by the annual Carbon Dioxide equivalent (CO 2 e) emissions calculated by the plant dispatch model.Fig. 2g and i show predicted CO 2 e emissions savings as generation capacity was increased for both silicon PV and CFPV respectively.As expected, CO 2 e savings increased with generation capacity for both PV technologies, however, we observed the rate at which this occurs is non-linear as it becomes progressively more difficult to satisfy demand that does not align to irradiance.These data revealed that the CFPV device is approximately twice as effective at decarbonizing the grid for an equivalent amount of silicon PV over the range of C examined.Hence grid-scale CFPV was predicted to be more successful in reducing Carbon emissions than the equivalent capacity of installed silicon PV.When one reflects on the scale of PV installation that has been forecast to achieve Net Zero at the national level, [4][5][6] and the consequent PV market penetration this implies, we argue that these data make a strong case for CFPV to be part of the energy generation mix to address some of the inflexibility that silicon PV has in meeting 'hard to decarbonize' energy demand.
The reason for the greater impact of CFPV as compared to silicon PV was its superior yield at irradiances below 1000 Wm À2 .Fig. 3 shows a histogram of the irradiance values used in the model corresponding to July.Diurnal variation and weather results in a mean irradiance during daylight hours of 259 Wm À2 , for which the CFPV device reported by Bristow and Kettle 33 had a PCE enhancement of factor E(259 Wm À2 ) = 2.94 as compared to standard testing conditions (Fig. 1).Thus, the CFPV device was providing a power output in real conditions that was closer to its rated capacity than the silicon equivalent.

Enhanced capacity factors for PV
The beneficial behaviour of the CFPV device in the previous section can be quantified by the capacity factor, which as a reminder, is the ratio of the actual energy generated over a period to the theoretical maximum energy generated over the same period.Model predictions of the capacity factor for devices considered here are shown in Table 1.Typically the capacity factor of solar installations varies between 10% and 25% depending on the level of insolation. 11In the UK where we based our analysis, the temperate climate and high latitude results in PV capacity factors of around 10%, 15 which agrees well with present model predictions for silicon PV of 8.89%.The CFPV device reported by Bristow and Kettle, 33 by contrast, is predicted to have a capacity factor of 27.40% in the UK, more than 3 times larger than silicon PV.

Benefits of CFPV behaviour on income generation on wholesale markets
As with Carbon emissions, the real-time balance between supply and demand is also critical in determining revenues from PV generation assets.1][12] Conversely, if demand is not met from renewables then the wholesale price of energy climbs, representing an unmet need that may be met by high carbon intensity generation.To demonstrate the possibilities of revenue generation from CFPV, we estimated the annual income from a 5 MW P solar farm and compared it to that expected from silicon PV.Our rationale for this approach is that a 5 MW P solar farm would be large enough to sell electricity on the wholesale market but not so large as to significantly perturb the market price.In the calculations, we accumulated revenue in each settlement period over the course of a year and ignored the possibility of penalties for under-and over-generation, 43 and assumed that the PV installation makes no change to the  View Article Online marginal cost of energy.A full description of the calculations is provided in Section S3 of the ESI.† The silicon solar farm was estimated to yield h194 000 over the year, whilst an equal capacity installation of CFPVs with characteristics reported by Bristow and Kettle 33 was estimated to yield h611 000, more than 3 times as much.This additional income is due to increased generation when irradiance is below 1000 Wm À2 , which in a UK context, is a large proportion of the time (see e.g.Fig. 3).However, the greater income that the CFPV device provides should be viewed in the context of lower efficiencies under standard testing conditions (PCE = 0.8% under AM1.5), since this would be expected to lead to greater module costs (particularly deriving from the TCO 44 ) and land costs for the same generating capacity.To quantify this anticipated trade-off, we used the approach described in ESI † Section S3 to estimate the cost of commercially produced dye-sensitised CFPVs of the type described by Bristow and Kettle 33 at 28.54 hm À2 , and in turn, predicted the module cost per unit capacity (h/W P ) shown in Table 1.These module costs were predicted to increase with reducing PCE under standard testing conditions, with CFPV modules from ref. 33 costing 16 times more than the Silicon equivalent.Allied to this, land rent costs also increased as PCE under standard testing conditions reduced, as shown in ESI † Table S3, though land rent costs are predicted to be smaller than that of the modules themselves for a 5 MW P solar farm.
Hence, for CFPV modules with characteristics as reported by Bristow and Kettle, 33 we have demonstrated an intrinsic increase in capacity factor and thus more efficient utilisation of a grid connection, but that the low PCE at AM1.5 in this case leads to substantial increases in module and land costs.We now move on to discuss the second aspect of our investigation, namely to ascertain whether the CFPV behaviour of devices can be designed.Were this to be the case, CFPV devices could be designed to balance the characteristic behaviours highlighted for the Bristow and Kettle 33 device.

Device fabrication and measurements
We selected a dye-sensitised architecture shown in Fig. 4 as a candidate CFPV due to its high efficiency in low light conditions. 45The basic design of the present CFPVs followed that of Saygili et al., namely comprising the organic Y123 dye and the copper(II/I) bis(4,4 0 ,6,6 0 -tetramethyl-2,2 0 -bipyridine) bis(trifluoromethanesulfonyl)imide (known as Cu(tmby) 2 ) electrolyte. 46The cells were assembled with poly(3,4-ethylenedioxythiophene) counter electrodes, allowing the photoanode to be in direct contact with the cathode. 47The devices were assembled based on two-layered titania photoanodes, comprising an initial layer of photoactive 30 nm nanoparticles with thicknesses of t TiO 2 = 12, 18, 24 and 48 mm, each capped by a 6 mm scattering layer consisting of 400 nm TiO 2 nanoparticles acting as a back reflector.At low light intensities, the effective diffusion length of ions in the electrolyte can be assumed to be the total TiO 2 thickness to first approximation as the counter electrode attaches directly behind the scattering layer.Thus, by changing t TiO 2 the diffusion length of ions in the electrolyte can be controlled.
Fig. 1 shows PCE as a function of irradiance for CFPV devices with varying t TiO 2 .PCE was largely constant with irradiance for the device with small t TiO 2 (= 12 mm), and thus has similar PCE-irradiance behaviour as commercial silicon, 48 albeit with a lower efficiency.As t TiO 2 increased beyond 12 mm, it was observed that PCE reduced.Importantly in the context of this paper, the reduction in PCE depended on irradiance, with PCE under high irradiance reducing more than under low irradiance.We ascribed this reduction to the photocurrent generation of dye-sensitised PVs being limited by diffusion mass transport, 49 which in turn reduced performance to an extent that depends upon both t TiO 2 and irradiance.Critically, we demonstrated that the PCE-irradiance behaviour for these devices was controlled by the PV layer stack.

Energy systems modelling utilising designed CFPV devices
Fig. 1 shows that the PCE -irradiance characteristic for the present devices form a series with the Bristow and Kettle device. 33As t TiO 2 is increased from 12 mm to 48 mm, the PCE at 1000 Wm À2 is reduced, whilst the PCE at low intensity is largely unchanged.The device reported by Bristow and Kettle device 33 is an extreme version of the t TiO 2 = 48 mm device, with even lower efficiency at 1000 Wm À2 .
Model predictions for the designed CPFV devices are summarised in Table 1.The devices with t TiO 2 = 12 mm, 18 mm and 24 mm, for which there is limited increase in PCE as irradiance reduces (E(140 Wm À2 ) r 1.1), show limited improvements in capacity factor, decarbonisation and revenue generation.These data are shown in more detail in ESI † Fig. S2 and S3.
These data contrast to that for the t TiO 2 = 48 mm device, for which the PCE increased by a factor of E(140 Wm À2 ) = 1.9 (Table 1), which in turn translated to a more substantial modification of generation and associated benefits.Focusing on capacity factor in particular, the device with t TiO 2 = 12 mm had a capacity factor of 8.87%, which compared to 14.5% for t TiO 2 = 48 mm, more than 60% larger.This enhancement in PV capacity factor by device design is larger than for both singleaxis (B10-35%) and dual-axis (B30-45%) tracking systems 50,51 and does not require mechanical tracking systems.Looking in more detail at these data, Fig. 2b, e and h show predicted annual generation mix, change in energy dispatch, and CO 2 e savings respectively as capacity of t TiO 2 = 48 mm CFPV devices is increased.It can be seen that even for the modest value of E(140 Wm À2 ) = 1.9 given by this device results in up to 60% improvement in carbon savings compared to the silicon equivalent.These data emphasise that the benefits associated with CFPV are due to an increase in PCE with reducing light intensity, and not the absolute value of PCE at low irradiance.
We now turn to examine the costs associated with the designed CFPV devices.As it is the PCE under 1000 Wm À2 that determines the rated power of a solar installation, an increase in PCE under these conditions will lead to a reduction in cost.Thus, the predicted module costs for the designed CFPV devices are all substantially lower than for the Bristow and Kettle 33 CFPV device which has lower PCE.Focusing on the t TiO 2 = 48 mm CFPV device, the predicted module cost is only 3 times higher than the silicon equivalent, contrasting with 16 times higher for the Bristow and Kettle 33 CFPV device.
These data have thus shown that changing t TiO 2 thickness offers control over both CFPV benefits and module cost.However, this was realised by controlling efficiency at AM1.5 (Fig. 1), such that there was a trade-off between costs (related to PCE at AM1.5) and enhanced capacity factor (related to increase in PCE with reducing light intensity).As such, changing t TiO 2 thickness alone did not realise low costs and enhanced capacity factor simultaneously.That said, we highlight that cost is not the only consideration from a system perspective, as electricity supply operators must ensure reliable power supply from a diverse range of sources to meet demand when faced with varying generation from renewables.For example, Nuclear is an important part of the energy mix in the UK despite its high levelised cost of energy because of the reliable base load it provides. 52hus, more expensive and less variable solar generation may still represent value from a system perspective.
Nonetheless, the costs of the designed CFPV devices motivates us to consider how one may achieve low costs and CFPV benefits simultaneously.In ESI † Section S4, we present data for Dye Cells engineered to give high capacity factor behaviour by another route, namely by changing electrolyte concentration.These data show that we again control the PCE vs. irradiance characteristics through device design, but again this is through a reduction in PCE at AM1.5, in a similar fashion to Fig. 1.Notwithstanding this, we expect that there is still opportunity for small improvement in costs associated with dye-sensitised CFPVs as the present record efficiency for a dye-sensitised PV device under AM1.5 conditions is 13.5%, 53 which is higher than the 10% achieved for the t TiO 2 = 12 mm device here.
We suggest that the larger opportunity may be in the creation of CFPV devices with Organic [23][24][25][26][27] or Perovskite [28][29][30][31] absorber layers, as higher PCEs in these devices can mitigate costs whilst still realising the benefits of increasing PCE as light intensity reduces.To demonstrate this opportunity, we repeated the above plant dispatch analysis using data for a quarternary Organic PV device reported by Nam et al., 23 and a MAPI Perovskite PV device from Du et al., 28 both of which display CFPV behaviour.Fig. 5 shows the predicted capacity factor for these devices as a function of enhancement factor at l = 140 Wm À2 alongside all other devices considered in this paper.It is observed that the predicted capacity factor varies approximately linearly with enhancement factor for all device types, showing the generality of the approach.We highlight that the enhancement factor is accessible in lab experiments, offering a straightforward first-order method to assess suitability of candidate PVs for CFPV applications.More detailed assessments of suitability would require measurement of the PCE-irradiance characteristic and analysis using the available code.Finally, while the capacity factors for the Perovskite and Organic PV device are modest compared to the Dye-Cell devices developed here, we recall that these devices were not designed for CFPV applications and so optimisation is likely to yield improvements.

Conclusions
In this paper we have introduced the concept of High Capacity Factor PV where the variation in output power is minimised by engineering PCE to increase as irradiance decreases.Energy systems modelling at a national level demonstrate that CFPVs of this type are more effective in reducing carbon emissions than a similar capacity of silicon PVs due to the reduced need for high carbon-intensity generation, and subsequently greater revenue potential as supply better meets demand.We also show experimental data for Dye-Cell based CFPVs in which the PCE vs. characteristic is controlled, which in turn is shown to tune the cost, carbon abatement and capacity factor offered by the technology.We believe that this approach presents an alternative, complementary approach to decarbonising electrical grids, as rather than relying solely on energy storage and demand management to account for inflexible, intermittent renewable generation, one incorporates flexibility in the generation itself.Further, we highlight literature reports which suggest that Perovskite and Organic PVs can also be used realise the high capacity factor concept, opening up the possibility of new applications for emerging PV technologies.

Characterization of photovoltaic cells
Current-voltage measurements under AM 1.5G illumination were carried out in ambient air using a HelioSim-CL60 solar simulator (Voss electronic GmbH).The irradiation intensity was asserted with a certified reference diode (Fraunhofer).An X200 source meter (Ossila, Sheffield, UK) was used to assess the solar cell performance (scan speed 25 mV s À1 , 200 ms).A circular mask was employed to confine the active solar cell area to 0.196 cm 2 .The shown efficiency trends with illumination level are averages of four to six cells at all times, pending reasonable error margins of the manual cell fabrication.

Fig. 2
Fig. 2 Annual generation profiles of the UK (a)-(c), change in generation (d)-(f) and carbon savings (g)-(i) as a function of additional silicon PV (a), (d), (g), and CFPV for t TiO 2 = 48 mm devices shown in Fig. 1b (b), (e), (h) and CFPV device 33 (c), (f) and (i).Change in generation (d), (e) and (f) figures show change in generation against 2016 historical data.Carbon savings (g), (h) and (i) figures show the source of carbon savings from reduction in Gas (Light Blue) and Coal (Dark Blue) emissions.

Fig. 3
Fig. 3 Histogram of irradiance in the UK during July as an example of data used in calculations.

Fig. 5
Fig.5Predicted UK capacity factor for PV devices considered in this study as a function of enhancement factor at 140 Wm À2 .Purple closed squares: dye-cell CFPV with t TiO 2 from 12 mm (light) to 48 mm (dark, purple) -Table1; purple open triangles: dye-cell CFPV with Cu M 2+ from 0 M (light)

Table 1
Experimental data related to CFPV devices as well as predicted CO 2 e savings for C = 1, capacity factor, and wholesale earnings and costs for a 5 MW P solar farm.Methodologies for prediction of these numbers are included in the ESI as described in the main text Energy & Environmental Science Paper Open Access Article.Published on 19 September 2023.Downloaded on 10/9/2023 2:49:40 PM.This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.