Intermolecular π-stacking stabilization of a new high-M/L-ratio coordination motif for a dinuclear Fe(III) complex supported by a “salen-type” Schiff base derivative of o-xylylenediamine

Ilia D. Shutilov; Pavel A. Volodin; Alexander S. Ovsyannikov; Andrew V. Pyataev; Lyubov V. Frantsuzova; Daria P. Gerasimova; Ayrat R. Khamatgalimov; Svetlana E. Solovieva; Igor S. Antipin

doi:10.1039/D5DT00856E

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Intermolecular π-stacking stabilization of a new high-M/L-ratio coordination motif for a dinuclear Fe(iii) complex supported by a “salen-type” Schiff base derivative of o-xylylenediamine†

Ilia D. Shutilov,^a Pavel A. Volodin,^b Alexander S. Ovsyannikov,

*^a Andrew V. Pyataev,^b Lyubov V. Frantsuzova,

^a Daria P. Gerasimova,

^a Ayrat R. Khamatgalimov,

^a Svetlana E. Solovieva^a and Igor S. Antipin

Author affiliations

* Corresponding authors

^a A. E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Arbuzova 8 str., 420088 Kazan, Russian Federation
E-mail: osaalex2007@rambler.ru

^b Kazan Federal University, Kremlevskaya 18 str., 420008 Kazan, Russian Federation

Abstract

Control over the self-assembly of cluster complexes is of high importance. In this respect, intermolecular noncovalent interactions play a crucial role. An unprecedented dinuclear Fe(III) complex, supported by an o-xylylenediamine Schiff base derivative and stabilized by intermolecular π-stacking is reported, paving a way for designing new functional 3d metal complexes.

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DOI: https://doi.org/10.1039/D5DT00856E
Article type: Communication
Submitted: 09 Apr 2025
Accepted: 09 Jun 2025
First published: 09 Jun 2025

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Dalton Trans., 2025,54, 10222-10226

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Intermolecular π-stacking stabilization of a new high-M/L-ratio coordination motif for a dinuclear Fe(III) complex supported by a “salen-type” Schiff base derivative of o-xylylenediamine

I. D. Shutilov, P. A. Volodin, A. S. Ovsyannikov, A. V. Pyataev, L. V. Frantsuzova, D. P. Gerasimova, A. R. Khamatgalimov, S. E. Solovieva and I. S. Antipin, Dalton Trans., 2025, 54, 10222 DOI: 10.1039/D5DT00856E

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Dalton Transactions

Intermolecular π-stacking stabilization of a new high-M/L-ratio coordination motif for a dinuclear Fe(iii) complex supported by a “salen-type” Schiff base derivative of o-xylylenediamine†

Abstract

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Article information

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Intermolecular π-stacking stabilization of a new high-M/L-ratio coordination motif for a dinuclear Fe(III) complex supported by a “salen-type” Schiff base derivative of o-xylylenediamine

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