Issue 26, 2025

Intermolecular π-stacking stabilization of a new high-M/L-ratio coordination motif for a dinuclear Fe(iii) complex supported by a “salen-type” Schiff base derivative of o-xylylenediamine

Abstract

Control over the self-assembly of cluster complexes is of high importance. In this respect, intermolecular noncovalent interactions play a crucial role. An unprecedented dinuclear Fe(III) complex, supported by an o-xylylenediamine Schiff base derivative and stabilized by intermolecular π-stacking is reported, paving a way for designing new functional 3d metal complexes.

Graphical abstract: Intermolecular π-stacking stabilization of a new high-M/L-ratio coordination motif for a dinuclear Fe(iii) complex supported by a “salen-type” Schiff base derivative of o-xylylenediamine

Supplementary files

Article information

Article type
Communication
Submitted
09 Apr 2025
Accepted
09 Jun 2025
First published
09 Jun 2025

Dalton Trans., 2025,54, 10222-10226

Intermolecular π-stacking stabilization of a new high-M/L-ratio coordination motif for a dinuclear Fe(III) complex supported by a “salen-type” Schiff base derivative of o-xylylenediamine

I. D. Shutilov, P. A. Volodin, A. S. Ovsyannikov, A. V. Pyataev, L. V. Frantsuzova, D. P. Gerasimova, A. R. Khamatgalimov, S. E. Solovieva and I. S. Antipin, Dalton Trans., 2025, 54, 10222 DOI: 10.1039/D5DT00856E

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