Imidazolium and picolinium-based electrolytes for electrochemical reduction of CO 2 at high pressure †

Ionic liquids (ILs) have been considered among one of the most promising materials under investigation for integration of CO 2 capture and electrochemical reduction (ECR). In the design of an IL-based electrolyte that can be employed industrially, the understanding of the influence of IL structure on ECR was considered essential. In this context, electrolytes with trifluoromethanosulfonate (OTf) anion were investigated as aqueous electrolytes for electrochemical reduction of CO 2 at high pressure and near room temperature with zinc electrodes. The eﬀect of replacing the 1-ethyl-3-methyl-imidazolium cation [EMIM] by 1-ethyl-3-picolinium [C 2 (3)pic] and by 1-ethyl-4-picolinium [C 2 (4)pic] cations was studied. The use of picolinium-based electrolytes in ECR is for the first time reported. A high-pressure single compartment test bed was used for electrolyte screening. Carbon monoxide productivities and selectivities were determined for the several electrolytes with diﬀerent water contents. The electrolytes were characterized by cyclic voltammetry and electrochemical impedance spectroscopy. Electrolyte conductivities and diﬀusion coeﬃcients were estimated. The eﬀect of the cations is complex as it aﬀects conductivity, double layer structure, reaction reversibility and even the ionic liquid physical state. Notwithstanding, it is possible to tune these properties to achieve similar CO productions with reduced IL amounts, considering the nature of the cation and the water content, leading to the design of more cost eﬀective electrolytes for eﬃcient ECR process.


Introduction
Ionic liquids (ILs) are emerging as an eco-friendly alternative resource with applications in a wide range of technological fields.One of these applications is in electrochemical CO 2 reduction (ECR).In fact, they have been considered among one of the most promising materials under investigation for this process. 1ECR is a CO 2 utilization research technology that is being intensively investigated not only for obtaining chemical building blocks and fuels, but as an excellent future option to store energy from renewable sources, such as solar and wind energy, that are seasonal, intermittent and geographically dependent.
Some families of ILs exhibit high CO 2 absorption capacity, 2,3 reasonable ionic conductivities, wide electrochemical stability windows, 4 high thermal and chemical stability, 5 negligible volatility 6 and the ability to stabilize CO 2 charged species facilitating ECR.These properties make them particularly suited as electrolytes for CO 2 reduction.There have been several explanations for the role of ILs in promoting ECR.Some authors proposed that the imidazolium cations act as co-catalysts by reducing the activation energy for the formation of the CO 2 radical anion, 7 or by the formation of imidazolinium radicals.In the first case, possibly through protons at the C2, N1, and N3 positions, 8 or by hydrogen bonding with C4 and C5 positions.In the second case by the reduction on an Ag electrode surface, while other types of cations, such as ammonium and pyrrolidinium are effective by modifying the electrochemical double layer. 9esides the ILs capability to act as co-catalyst, they offer the possibility of further integration with CO 2 capture, once ionic liquids are also being used as CO 2 capture agents at pilot scale. 10This also contributes to increase the energy efficiency of the whole process of CO 2 capture and conversion.
In an earlier study, 11 the authors have reported for the first time, a process for co-electrolysis of CO 2 and water into syngas, near room temperature in a pressurized reactor using an IL-based electrolyte according to the reactions given by eqn (1)- (3).Equilibrium cell potentials in standard conditions are also indicated. 12,13 2 + 2H + + 2e À -CO + H 2 O E 0 = À0.10V vs. SHE (1) This reactor can operate up to 100 bar and 80 1C, with a configuration similar to an alkaline electrolyser, for hydrogen production suitable to be used industrially.A zinc cathode was selected due to its high selectivity for CO and low cost.This metal has been shown to be an effective catalyst for ECR. 14,15Ls are also characterised by their tuneable properties.These properties arise from the possibility of combining different cations and anions yielding a large number of possibilities.7][18][19][20][21] According to literature only a relative limited number of IL-based electrolytes have been reported.In order to design an IL-based electrolyte that can be employed industrially, the understanding of the influence of IL structure on ECR is crucial.In this work, aqueous solutions of ILs belonging to the family of imidazolium and picolinium ionic liquids are characterized and compared to each other.To the authors best knowledge this is the first report of the use of picolinium-based electrolytes in ECR.In particular, the effect of replacing the 1ethyl-3-methyl-imidazolium cation [EMIM] by the 1-ethyl-3picolinium [C 2 (3)pic] and 1-ethyl-4-picolinium [C 2 (4)pic] cations of ILs combined with trifluoromethanosulfonate (OTf) anion are investigated as electrolytes for electrochemical reduction of CO 2 at high pressure with zinc electrodes.
Fig. 1 shows the chemical structure of the ionic liquids employed in this work.[C 2 (4)pic][OTf] is solid at room temperature, but liquid at the temperature of 45 1C, under which all electrolytes were tested.
ILs are generally more viscous than water, leading to mass transfer limitations.Few studies report the influence of water in ECR in aqueous IL electrolytes. 22The use of aqueous IL solutions is advantageous as water can play the role of viscosity reducing agent, proton source as well as active reaction mediator.These solutions will also be more cost effective than pure ILs.However, increased water contents may decrease CO 2 absorption by the electrolyte affecting negatively both CO 2 capture and ECR processes.The authors are undertaking screening studies of aqueous IL systems in order to design aqueous IL solutions that can be used as media to integrate CO 2 capture with conversion, and it is possible to work well at higher water contents.Thus, the effect of different water contents is studied.The nature of the electrolyte considerably influences the performance of ECR. 23Due to the complexity of the reaction system, it is not straightforward to establish structure-activity correlations.The authors also used electrochemical impedance spectroscopy to determine parameters useful in order to establish correlations for IL-based electrolyte screening.4)pic][OTf]) were synthetized in our lab according optimized synthetic procedure.The chemicals required for the preparation of ILs, were used without further purification including 3-and 4-methylpyridine (99%, Sigma-Aldrich), 1-bromoethane (98%, Alfa Aesar), and sodium triflluoromethanesulfonate (98+%, Alfa Aesar). 1 H and 19 F NMR spectra in DMSO (from Euriso-Top) were recorded on a Bruker AMX400 spectrometer at room temperature.Chemical shifts are reported downfield in parts per million (ppm).Elemental analysis was obtained on a Thermofinnigan Flash EA 1112 Series instrument, and it was performed by the Laborato ´rio de Ana ´lises at LAQV-REQUIMTE.

Experimental
Carbon dioxide and Nitrogen from Air Liquide (N45 purity 99.995% and 99.999 purity respectively) were used.

Synthesis of ionic liquids
The first synthetic step was based on microwave reaction by mixing the equivalent molar ratio between 3-or 4-methylpiridine with 1bromoethane in acetonitrile at 120 1C during 30 min.After reaction, the mixture was purified by evaporation of the solvent and then extractions with diethyl ether.The final product was dried under vacuum.The second step was based on the anion exchange reaction using the previous bromide salts [C 2 (3)pic][Br] and [C 2 (4)pic][Br] dissolved in ethanol and a slight excess (1.1 molar equivalent) of the sodium trifluoromethanesulfonate. The mixture was stirred at room temperature during 24 h.The mixture was filtrated and the desired product was isolated and dried under vacuum.[C 2 (3)pic][Br].The product was obtained as a hygroscopic white solid (yield: 95%). 1

Electrochemical experiments
2.3.1.Cyclic voltammetry.Cyclic voltammetry (CV) was carried out using an Autolab PGSTAT128N-Autolab 84469 potentiostat, in an undivided high-pressure cell with a threeelectrode system.This cell was described in detail elsewhere. 14n Ag/Ag + rod was used as a quasi-reference electrode (QRE) and a commercial zinc foil as a counter sacrificial electrode (CE) and as a working electrode (WE).The electrodes are inserted in a Teflon support to assure a constante distance from each other during experiments (13 mm). 24The electrolyte was a solution with different percentage of water and the ionic liquid to be tested.All voltammograms were performed in a potential range from À0.5 V to À2.5 V vs. Ag/Ag + at 45 1C, 10 bar pressure of CO 2 or N 2 and at a scan rate of 50 mV s À1 .
2.3.2.Electrochemical reduction of CO 2 .The electrolyses were performed using the same facility as the one used for cyclic voltammetry experiments.The cell was assembled and filled with 10 bar of CO 2 and left about 1 hour to stabilize at 45 1C, under stirring.Then, current was applied to the electrodes and electrolyses were carried out under galvanostatic control.Next, a sample of the gaseous mixture was analyzed by gas chromatography using the sampling procedure elsewhere. 14he chromatograph used is an Agilent Micro GC 3000 equipped with a backflush 1 ml gas injector with a thermal conductivity detector (TCD).Two columns were used, namely a molecular Sieve 5A, 10 m Â 0.32 mm column with a Plot U 3 m Â 0.32 mm pre-column with argon as carrier gas and Plot U 8 m Â 0.32 mm column with Plot Q, 1 m Â 0.32 mm as pre-column with helium as carrier gas.H 2 , N 2 , O 2 , CO and CH 4 are quantified in the molecular sieves column and CO 2 and higher hydrocarbons can be quantified with the Plot U column.Compositions were determined by comparison with calibrated gaseous mixtures of known compositions supplied by Air Liquide.
2.3.3.Electrochemical Impedance Spectroscopy.For electrochemical impedance spectroscopy experiments, the same cell configuration and working conditions were used as those for cyclic voltammetry and electrolyses.However, the counter electrode used for water oxidation was a commercial IrO 2 deposited on a titanium mesh, and the cell is inside a Faraday cage, to reduce interferences during analysis.This anode was chosen to generate data that can be readily transposed to a twocompartment membrane cell configuration. 11The electrolyte was a solution of water and ionic liquid.When the open circuit voltage was stabilized, a sinusoidal voltage signal of 5 mV was applied over a range of frequencies from 50 mHz to 100 kHz.This process was repeated varying the potential from À1.2 V to À1.8 V vs. Ag/Ag + .The experimental data obtained was analyzed with the ZView software.

Cyclic voltammetry characterization
The voltammograms of dry ILs at 45 1C in 10 bar N 2 atmosphere are presented in Fig. 2 for copper and zinc cathodes.Onset potentials were evaluated in the conditions under study and defined as the potential at which the current density reaches À1 mA cm À2 . 25 4)pic] + cations substantially changes the onset potential from À1.8 V vs. Ag/Ag + (QRE) to À0.96 V and À0.99 V vs. Ag/Ag + (QRE), respectively.On the contrary, the position of the methyl substitution on the pyridine ring doesn't affect significantly the onset potential.The oxidation peak at À0.70 V vs. Ag/Ag + (QRE) in the voltammogram of dry EMIMOTf in nitrogen atmosphere was assigned to the oxidation of reduced [EMIM] + cations 26,27 and is consistent with the results obtained by Wang et al. for copper surfaces, 28 who have indicated that reduce imidazolium cation layer serves as the Fig. 2 Cyclic voltammograms at 45 1C carried out at 50 mV s À1 in the active site for ECR.Thus, reduced [EMIM] + cations or related species are formed on the surface of Cu electrode and yield the oxidation peak on the reverse scan.In the same conditions, a more prominent oxidation peak at À1.18 V vs. Ag/Ag + (QRE) can be observed for the zinc electrode.This reduced [EMIM] + cation layer was shown to facilitate CO 2 reduction, while simultaneously suppressing hydrogen evolution on copper surfaces. 28he reduced species has been proposed to be [EMIM] + radical.This oxidation peak is not visible in the voltammograms of the picolinium ILs.Oxidation of zinc cathode may not allow the observation of this peak.
The effect of different water compositions on the voltammograms was also investigated.Fig. 3 shows the cyclic voltammograms of the aqueous IL-based electrolytes together with the voltammograms of the dry ILs in N 2 and CO 2 atmosphere for comparison.
For the dried electrolyte with [EMIM] + cation in CO 2 atmosphere, Fig. 3(a), the oxidation peak at À0.86 V vs. Ag/Ag + (QRE) is shifted to less negative potentials, when compared with the oxidation peak at À1.18 V vs. Ag/Ag + (QRE) in N 2 atmosphere.However, when water is added (10 wt%) the oxidation peak increases significantly and is correlated with a clear reduction process.This latter process involves not only CO 2 , but also the [EMIM] + cation, as the oxidation peak is observed in N 2 atmosphere.This illustrates also the role of water in promoting the catalytic activity of imidazolium cation.For the electrolytes with the [EMIM] + cation, the highest current densities can be observed for a water composition of 50 wt%.For this composition, a small reduction peak is observed at À0.70 V vs. Ag/Ag + (QRE) and a shoulder at À0.63 V vs. Ag/Ag + (QRE) probably corresponding to the oxidation process of the [EMIM] + cation.Onset potentials (E onset ) decrease with increasing water content but increase for water content of 90 wt% (see Table S1 of ESI †).These shifts in potential must be considered with care as they will depend on activity coefficients of water and H + at the different concentrations.When the water content is 90 wt%, current densities decrease significantly, possibly reflecting the decrease in CO 2 solubility when water content increases, 29 possible equilibrium potential shifts may not be disregarded. 30or the electrolytes with the [C 2 (3)pic] + cation (Fig. 3b)) E onset decreases with increasing water content (Table S1, ESI †) with the exception of the 50 wt% composition that shows the most negative E onset at À1.22 V vs. Ag/Ag + (QRE).The highest current densities are obtained with the electrolyte with 90 wt% of water.One intense irreversible reduction process is observed for the composition of 10 wt% water with a peak at À1.22 V vs. Ag/Ag + (QRE).Water plays clearly an important role in the reaction.This peak is shifted to À0.98 V vs. Ag/Ag + (QRE) when water composition increases to 50 wt%.No peaks are observed for 90 wt% water composition.
For the electrolytes with the [C 2 (4)pic] + cation (Fig. 3c)), E onset doesn't decrease significantly with increasing water content (Table S1, ESI †), but it becomes more negative for water content of 90 wt%.An oxidation peak at À0.62 V vs. Ag/Ag + (QRE) for 10 wt% of water assigned to the oxidation of the [C 2 (4)pic] + cation radical (Table S1, Fig. S2, ESI †) can be observed.The highest current densities are obtained with the electrolyte with 10 wt% water for the low overpotential region.For 90 wt% water the voltammogram shows two peaks at À0.73 V and À0.97 V vs. Ag/Ag + (QRE).These peaks are probably due to the reduction of physically adsorbed and chemisorbed Fig. 3 Cyclic voltammograms on zinc cathodes at 45 1C carried out at CO 2 through a complex of electrogenerated picolinium radical, respectively.Two reduction peaks shifted to more negative values À0.88 V and À0.99 V vs. Ag/Ag + (QRE) are also observed when water content decreases to 50 wt%.At more negative potentials the electrolyte with 50 wt% water shows the highest current densities.Fig. S2 (ESI †) compares the CVs of different electrolytes with the same water composition.For the composition of 10 wt% and 50 wt% of water the [EMIM] + cation shows the highest reduction current density.With the increase of the percentage of water to 90 wt% [C 2 (3)pic] + and [C 2 (4)pic] + cations show the highest cathodic current densities in the low overpotential region.4)pic] + electrolyte with 90 wt% of water it is possible conclude that these two results are quite similar, with CO production of ca. 14 mmol cm À2 .Fig. 4 also depicts the H 2 /CO ratios of the electrolyses.It can also be observed that the higher current densities obtained with the [EMIM][OTf] electrolyte with 50 wt% water correspond to a higher selectivity for hydrogen production.
A second set of electrolyses was carried out in the same conditions as previously but for applied current densities in the range of À6 to À7.3 mA cm À2 and 50 C charge passed.Fig. 5 shows H 2 and CO productions.This Figure shows that the same trend of increased CO production with increasing content of water in the picolinium-based electrolytes, persists at these higher currents.
The selectivity to the products is measured by the faradaic efficiency (FE) of the electrochemical reaction, calculated by the following equation, where the j i is the partial current of the product i and | j Total | the current passed during electrolysis.The partial currents for each product was estimated by the quantities of products produced in the electrolysis determined by gas chromatography, as described in detail elsewhere. 14From Table 1 it is observed that the total FE is lower than 100%, possibly due to the difficulty of breaking the IL radical complex to generate CO at these low current densities.No gaseous products other than CO   and H 2 were detected.As this work addresses only the study of gaseous products, normalized faradaic Efficiencies (NFE) were calculated according to eqn (5), where j i is the partial current of the gaseous product CO or H 2 divided by the summation of estimated partial currents for CO and H 2 .
From Table 1 it can be observed that a higher selectivity for CO production is achieved when the electrolytes with [EMIM] + cation at 10 wt% of water and [C 2 (4)pic] + cation at 90 wt% of water are used with values of NFE of 64% and 61%, respectively.The lower selectivity for CO production was obtained with the electrolyte composition of [EMIM] + cation with 50 wt% of water.
Table 2 lists the production of gaseous products and faradaic efficiencies in electrolyses at 45 1C, 10 bar CO 2 atmosphere, with zinc as cathode, 50 C charge passed and applied current density of ca.À7 mA cm À2 .By inspection of Table 2 it can be verified that the selectivity for CO increases to 95% and CO production increases one order of magnitude for [EMI-M][OTf] with 10 wt% water at these higher applied current densities.
The results obtained by CV and electrolysis allow to discuss a possible mechanism for electrochemical activation of CO 2 by 1-ethyl-3-methyl imidazolium based on the mechanism proposed by Wang et al. for the ionic liquid 1-ethyl-3-methyl imidazolium tetrafluoroborate. 28This mechanism is depicted in Fig. 6.
The proposed mechanism reflects the competition of IL, protons and CO 2 for the catalytic sites at the surface of the cathode.When IL concentration is high, it leads to its significant adsorption on the surface of the cathode, ECR will proceed via pathway a) with formation of CO 2 -IL complex-based species.On the contrary, when protons occupy the catalytic sites in an appreciable extent, the hydrogen evolution reaction (HER) will be the favoured reaction (pathway b), instead of ECR.Pathway c) will be followed for CO 2 molecules directly adsorbed on the cathode surface.
This mechanism also allows explaining the obtained total FE significantly below 100%.When the catalytic cycle stops at IL carboxylate formation, 31 electric current used is not accounted for, as only CO and H 2 are quantified by GC.This seems to happen particularly with the picoline basedelectrolytes, which carboxylates are seemingly more stable than EMIM carboxylates, due to their aromatic configuration.

Electrochemical Impedance Spectroscopy characterization
3.3.1.Impedance Simulations.EIS data will be used to support the proposed mechanism and to provide further insights of the role of ILs in ECR.
The most widely used approach for interpretation of EIS data is equivalent circuit modelling, as the response of the cell can be described in terms of electric elements in order to represent the different physical and chemical processes occurring in CO 2 electro-reduction.Furthermore, it is possible to deconvolute charge and mass transfer processes.As a reasonable approximation of the electrochemical cell, Randles circuits were used to represent the charge transfer reactions at the metal/electrolyte interface and diffusion processes.Fig. 7 represents the equivalent circuit model that was selected to represent the processes under study.It consists of a resistance in   series with two Randles circuits also in series to account for the proposed mechanism.
Results are represented by Nyquist plots, in which three different regions are analysed and electric circuit elements assigned to cell processes: high frequency (electrolyte resistance, modelled by resistor R 0 ), medium frequency (charge transfer resistance and double layer effects, modelled by the RC circuit, the capacitor C is generalized as constant phase element CPE, and low frequency (diffusion processes modelled by Warburg elements, W).
The Nyquist plots of the [EMIM][OTf] electrolytes with different water compositions at applied potentials of À1.2 V, À1.4 V and À1.8 V vs. Ag/Ag + (QRE) exhibit depressed semicircles depicted in Fig. 8.The impedance parameters obtained after the fitting of the experimental results by using the equivalent circuit displayed in Fig. 7 are presented in Tables 3, 4 and 5 with respective chi-squared values.The results suggest the existence of two time constants.The model shows, in general, a good agreement with experimental results.As the water concentration increases diffusional components are more evident in the spectra, with the results for 90 wt% water fully fitted by the equivalent circuit of Fig. 7 with two Warburg elements Ws.
At À1.2 V vs. Ag/Ag + (QRE) the results for the electrolyte with 10 wt% H 2 O are simplified to two RC (CPE) circuits in series without Warburg elements.
Considering the mechanism depicted in Fig. 6 the first time constant process is assigned to the reduction of the [EMIM] + cation, previously adsorbed on the surface forming a film. 32he competition of water molecules for the catalytic sites interferes with the formation of the adsorbed IL film, this is notable when the concentration of water increases from 10 wt% to 50 wt%, leading to an increase of R1 and a diffusion limitation (Ws).
The behaviour of the 90 wt% water electrolyte is expectedly mainly determined by the significant lower quantities of dissolved CO 2 and consequently CO 2 diffusion plays an important role modelled by two Warburg elements, which might change the mechanism pathway.With the increase in water concentration to 90 wt% the resistance of the electrolyte (R 0 ) is notably increased, as expected.
The second electronic transfer can most probably be assigned to the step of the ECR process corresponding to the formation of the bulky complex CO 2 -IL radical anion subject to diffusional limitations.
The Nyquist plots at À1.4 V and À1.8 V vs. Ag/Ag + (QRE) exhibit significant changes.The two semicircles become more resolved.For the 90 wt% water composition the system is best described by one Randles circuit, indicating the absence of an IL film.The coefficient of the constant phase element n 1 for all water compositions studied showed a deviation from the real capacitance.This can most probably be explained considering that the ionic liquid reduced/adsorbed on the cathode induces dispersive behaviour.
In general, an increase in the resistance is observed for 50 wt% water composition (R1 and R2) which will promote the competition of the HER explaining the elevated selectivity for hydrogen production observed in electrolyses (pathway b).
In order to further examine the transition from electrolytes with high IL contents to high water contents, the 50 wt% water electrolytes were investigated by EIS.Fig. 9 shows the Nyquist plots obtained for the different ILs for a composition of 50 wt% of water for an applied potential of À1.2 V vs. Ag/Ag + (QRE) and Fig. 10 shows the Nyquist plots obtained for the different IL for a 50 wt% of water for an applied potential of À1.4 V vs. Ag/Ag + (QRE).The fitting parameters are given in Tables 6 and 7.At À1.2 V vs. Ag/Ag + (QRE) all fitted resistances for [C 2 (4)pic] + are very high reflecting the high resistance of the electrolyte R 0 in agreement with the low CO productivities obtained in the electrolyses.The models show in general a good agreement with experimental results.
The error is higher for the [C 2 (3)pic] + -based electrolytes and for data obtained at À1.4 V vs. Ag/Ag + (QRE) that presents a higher value of chi-squared.This is due to the instability of the low frequency data points that renders the comparison of fitted values difficult.Two times constants can be observed for all the electrolytes.
In Table 8 the conductivity of different electrolytes calculated from EIS data at different applied potentials is presented.Conductivity was calculated according to eqn (6), where, d is the distance between the electrodes and A is the geometrical area.Within experimental errors, conductivities are independent of applied potential as they should be.The conductivity of the [EMIM][OTf] electrolyte with 90 wt% of water is the lowest, due to the significant decrease in the concentration of ionic charge   shows a conductivity one order of magnitude lower.The conductivity of [EMIM][OTf] at 25 1C and atmospheric pressure is 2.9 mS cm À1 , 33 water addition as expected is thus effective for increasing conductivity.Although the results clearly show a trade-off between higher viscosity with lower ion mobility and higher water concentrations that leads to lower ion concentration and thus, a lower number of charge transporters. 34n the cases, where EIS provided the necessary data, diffusion coefficients were also calculated according to eqn (7), where, l is the Debye length and t is the value of n obtained in the fittings with the Zview.
The diffusion coefficient of CO 2 in [EMIM][OTf] determined at 25 1C and atmospheric pressure was 1 Â 10 À10 m 2 s À1 35 and in water at 25 1C at infinite dilution is 1.92 Â 10 À9 m 2 s À1 . 36The diffusion coefficients of the lower frequency semi-circle determined in the present work indicated in Table 9 are several orders of magnitude lower than these values.Most probably, the calculated diffusion coefficient for the high frequency semicircle corresponds to the diffusion of CO 2 in the IL, while the diffusion coefficient calculated for the lower frequency semicircle corresponds to the diffusion of the bulkier IL complex.

Conclusions
This work illustrates how differences in structure of ionic liquids have a profound influence in their behaviour as electrolytes.For instance, changing only the position of the methyl group in the picolinium cation turns [C 2 (4)pic] + into a solid at room temperature, while [C 2 (3)pic] + is a liquid at this temperature.This has significant consequences on the conductivity of the electrolytes and hence on their performance.The present work shows that the [EMIM] + and [C 2 (4)pic] + cations behave as co-catalysts with Zn electrodes due to the formation of the corresponding radicals.The degree of reversibility depends on the cation structure and nature of the electrode.[C 2 (3)pic] + seems to be effective by modifying the electrochemical double layer.These facts are in accordance with the results of Zhao et al. 9 Based on productivity and electrochemical data, the behaviour of [EMIM] + -based electrolytes with different water contents seems to be determined mainly by the variation of CO 2 solubility and conductivity.With the current available data, for the studied picolinium-based electrolytes, at low current densities, there is no obvious influence of conductivity, while the reversibility of the reaction and conductivity at higher currents seem to play a more determinant role.The investigated picolinium-based electrolytes yield low CO productivities at low water contents.However, their performance is significantly increased by the addition of water.Further screening studies are necessary to find an IL-based electrolyte with a high content of water that can achieve a CO production preferably higher than [EMIM][OTf] with 10 wt% of water.
It can be clearly observed, in the aforementioned Figure, that the replacement of the cation [EMIM] + by [C 2 (3)pic] + and [C 2 (

3. 2 .
Electrochemical reduction of CO 2 CO 2 electrochemical reduction was carried out at 45 1C in 10 bar CO 2 atmosphere, with zinc as cathode and sacrificial anode and 10 C charge passed.A first set of electrolyses were undertaken at an applied current density range of À0.65 to À0.85 mA cm À2 .In Fig. 4 the productions of H 2 and CO obtained are presented for the different electrolyte solutions.It can be observed that for the [Emim] + based-electrolyte when water content in the electrolyte is increased the production of CO tends to decrease, on the other hand for picolinium cations [C 2 (3)pic] + and [C 2 (4)pic] + the opposite trend is observed.Comparing CO production obtained with the [EMIM] + electrolyte with 10 wt% of water, with the [C 2 (

Fig. 4
Fig. 4 Electrolysis on Zinc cathodes at 45 1C, 10 bar CO 2 applied current density in the range of À0.65 to À0.85 mA cm À2 and 10 C of charge passed.

Fig. 5
Fig. 5 Electrolysis on Zinc cathodes at 45 1C, 10 bar CO 2 applied current density of À7 mA cm À2 and 50 C of charge passed.

Fig. 6
Fig.6Mechanism for electrochemical activation of CO 2 by 1-ethyl-3methyl imidazolium based on the mechanism proposed by Wang et al.28

Fig. 9
Fig.9EIS on the Zn cathodes in a solution of 50 wt% water an ionic liquid at 10 bar CO 2 with an applied potential of À1.2 V vs. Ag/Ag + (QRE); the continuous line corresponds to the fitting.

Fig. 10
Fig.10EIS on the Zn cathodes in a solution of 50 wt% water an ionic liquid at 10 bar CO 2 with an applied potential of À1.4 V vs. Ag/Ag + (QRE); the continuous line corresponds to the fitting.

Table 2
Production of gaseous products and faradaic efficiencies in the electrolyses at 45 1C, 10 bar CO 2 atmosphere, with zinc as cathode and sacrificial anode, 50 C charge passed and applied current density of À7 mA cm À2

Table 4
Results of EIS fittings according with the equivalent circuits for [EMIM] + at À1.4 V vs. Ag/Ag + (QRE), to the different percentages of water

Table 5 Results
of EIS fittings according with the equivalent circuits for [EMIM] + at À1.8 V vs. Ag/Ag + (QRE), to the different percentages of water