High performance and remarkable cyclic stability of a nanostructured RGO–CNT-WO3 supercapacitor electrode

One of the most pressing concerns in today's power networks is ensuring that consumers (both home and industrial) have access to efficient and long-lasting economic energy. Due to improved power accessibility and high specific capacitance without deterioration over long working times, supercapacitor-based energy storage systems can be a viable solution to this problem. So, here, tungsten trioxide (WO3) nanocomposites containing reduced graphene oxide and carbon nanotubes i.e. (RGO-WO3), (CNT-WO3), and (RGO–CNT-WO3), as well as pure WO3 nanostructures as electrode materials, were synthesized using a simple hydrothermal process. The monoclinic phase of WO3 with high diffraction peaks is visible in X-ray diffraction analysis, indicating good crystallinity of all electrode materials. Nanoflowers of WO3 were well-decorated on the RGO/CNTs conductive network in SEM micrographs. In a three-electrode system, the specific capacitance of the RGO–CNT-WO3 electrode is 691.38 F g−1 at 5 mV s−1 and 633.3 F g−1 at 2 A g−1, which is significantly higher than that of pure WO3 and other binary electrodes. Furthermore, at 2 A g−1, it achieves a coulombic efficiency of 98.4%. After 5000 cycles, RGO–CNT-WO3 retains 89.09% of its capacitance at 1000 mV s−1, indicating a promising rate capability and good cycling stability performance.


Introduction
The development of energy storage systems (ESSs) is crucial for tackling climate change and the nite availability of fossil fuels, as well as for storing solar and wind energy efficiently. One of the most difficult challenges now facing academics is to build highly efficient, low-cost, and environmentally friendly ESS devices. With the rapid rise of the portable electronic device industry and the development of hybrid electric vehicles, the demand for high-energy and high-power density energy storage technologies has surged. Even at increased power densities, the stored energy should be able to be released smoothly and distributed. Among these ESSs, supercapacitors are one of the most important technologies for energy storage applications because they can give better power and energy densities than batteries and ordinary dielectric capacitors. [1][2][3][4] A number of materials have already been studied as supercapacitor electrode materials. Amongst all, RuO 2 and IrO 2 are good supercapacitor electrode materials because they have a high specic capacitance value and a high cycle capacity, which has sparked increased interest in this subject. However, their high cost and toxicity limit their practical application. One of the most active research subjects in electrochemistry is the creation of alternative economical and environmentally acceptable electrode materials with good performance. Many researchers are now working on alternate materials to IrO 2 and RuO 2 . One of the most enticing alternatives to RuO 2 and IrO 2 may be WO 3 owing to its electrochemical redox characteristics, environmental friendliness and low cost. [5][6][7] Tungsten trioxide (WO 3 ) is a wellknown wide band gap n-type semiconductor with a variety of unique features and many crystal forms that are suited for the intercalation of tiny cations such as H + . It's been explored extensively as a possible material for a variety of applications which includes solar energy devices, semiconductor gas sensors, photocatalysts, electrode materials for secondary batteries and supercapacitors, eld-emission devices. As a supercapacitor electrode, the capacitive characteristics of tungsten oxides e.g. mesoporous tungsten oxide, nanostructured tungsten trioxide, amorphous tungsten oxide and others have been studied. [8][9][10][11] Xu He et al. developed and synthesized tungsten trioxide microspheres electrode materials with a specic capacitance of 488.78 F g À1 . 12 M. Ashraf et al. presented an asymmetric supercapacitor (HRG/m-WO 3 ASC) made of monoclinic tungsten oxide (m-WO 3 ) nanoplates for the negative electrode and highly reduced graphene oxide (HRG) for the positive electrode and exhibited a specic capacitance of 389 F g À1 at a current density of 0.5 A g À1 . 13 Nevertheless, the main disadvantages of tungsten oxide pseudocapacitors are their limited electrical conductivity and weak rate performance. Supercapacitor resistance should be reduced to increase rate capability. However, tungsten oxide preparations with diverse morphologies have received a lot of attention in terms of capacitive characteristics. The majority of investigations, on the other hand, focused on WO 3 nanostructures produced from nanostructures, nanorods, or lms. Until now, the capacitive characteristics of WO 3 and carbon composites have received little attention in research. 14 Concerning greater surface area, environmental friendliness, linked pore structure, high electrical conductivity and pore size regulation, carbon materials with varied micro textures are considered the major choice for supercapacitors. [15][16][17][18] When WO 3 is mixed with carbon/graphene sheets that are extremely conductive, its conductivity greatly enhanced, resulting in good capacitive materials with excellent system conductivity. A 1D multi-walled CNTs (MWCNTs) and reduced graphene oxide interwoven network also enhance electrical conductivity while also providing greater electrochemically active surface area and efficient routes for both electrons and ions in a hybrid electrode. 19 The electrical double layer capacitor (EDLC) and pseudocapacitive processes in composites of WO 3 and RGO/MWCNTs are of particular interest because they contain a dual charge storage mechanism. 20 In addition, chemical vapour deposition, sol-gel, hydrothermal technique, and other methods have been used to synthesize WO 3 nanostructures in the current ndings. Among these, the hydrothermal approach was deemed superior because it allows the preparation of WO 3 nanoowers in a mild, well-controlled, and cost-effective manner, 21 which was ideal for our experiment. In the present work, a facile hydrothermal procedure is demonstrated to prepare monoclinic tungsten trioxide combined with carbon nanotubes and reduced graphene oxide i.e. RGO-CNT-WO 3 composite electrode. The electrochemical experiments revealed that the RGO-CNT-WO 3 composite electrode has better capacitive properties than the WO 3 , RGO-WO 3 , CNT-WO 3 electrode, with greater reversible charging/ discharging capabilities and larger capacitance values along with high cyclic stability. The ower-like architectures of WO 3 are very well assembled on reduced graphene sheets that are connected to CNTs with strong interfacial contact in RGO/CNT based tungsten trioxide nanocomposites, which ultimately provides the fastest electron transportation and thus enhances the performance of electrode.

Experimental section
The tungsten precursor was sodium tungstate dihydrate (Na 2 -WO 4 $2H 2 O). The pH was adjusted with hydrochloric acid (HCl). DI water was used to dissolve the precursor, dilute the acid to the appropriate molarity, and wash the nished product. Ethanol was also used to remove any contaminants from the nished product. Nickel foam was employed as the substrate for slurry casting the as-prepared powder. The samples were slurry cast onto the substrate using PVDF, Naon, and carbon black.
Sodium dodecyl benzenesulfonate (SDBS) was used to make CNTs solution in DI water. All of the reagents were acquired from Sigma Aldrich Co. LLC and utilized without additional purication. Nickel (Ni) foam was purchased from Winfay Group Co. Ltd, China.

Synthesis of WO 3 nanostructures
First of all, 2 g of Na 2 WO 4 $2H 2 O was dissolved in 50 ml DI water followed by the addition of 3 M HCl (i.e. 12.5 ml HCl in 50 ml DI water) until the pH reached 1. Aer that, 3.06 g of oxalic acid and 4 g of (NH 4 ) 2 SO 4 were added. The mixture was transferred to a stainless steel autoclave lined with Teon and holding 150 ml. The autoclave was sealed and placed in an oven at 180 C for 16 hours, aer which it was allowed to cool naturally. The precipitate was ltered and washed with DI water and ethanol multiple times before being vacuum dried for 12 hours at 80 C (light grey colour Fig. 1a).

Synthesis of RGO-WO 3 nanostructures
To begin, a 40 ml (1 mg/1 ml) graphene oxide solution was prepared using sonication and centrifugation. The RGO-WO 3 nanocomposite was then made by dissolving 2 g of Na 2 WO 4 -$2H 2 O in 30 ml of deionized water and stirring it for 30 minutes with a magnetic stirrer. Then, drop by drop, 3 M HCl was added until the pH reached up to 1.3.06 g of oxalic acid and (NH 4 ) 2 SO 4 were added aer that. The solution was then diluted with 50 ml of deionized water. Aer that, the GO solution was gently added using sonication for 45 minutes. The solution was then put down into a Teon-lined stainless steel autoclave and heated for 20 hours at 180 C. The RGO-WO 3 precipitate was ltered and washed multiple times with acetone and DI water and placed further in a vacuum oven to dry at 80 C for 12 h (Fig. 1b).

Synthesis of CNT-WO 3 nanostructures
First, 10 mg ml À1 MWCNTs were ultrasonically dispersed in 5 mg ml À1 sodium dodecyl benzenesulfonate (SDBS) for 8 hours. The CNT-WO 3 nanocomposite was then synthesized by dissolving 2 g of Na 2 WO 4 $2H 2 O in 30 ml of deionized water and stirring it for 30 minutes with a magnetic stirrer. Then, drop by drop, 3 M HCl was added until the pH reached 1.3.06 g of oxalic acid and 4 g of (NH 4 ) 2 SO 4 were added aer that. The solution was then diluted with 50 ml of deionized water. Aer that, the CNT solution was gently added using sonication for 45 minutes. The solution was then put into a Teon-lined stainless steel autoclave and heated for 20 hours at 180 C. The CNT-WO 3 precipitates were obtained through ltration and washing with acetone and DI water multiple times and placed further in a vacuum oven to dry at 80 C for 12 h shown in Fig. 1c.

Synthesis of RGO-CNT-WO 3 nanostructures
By sonication for 9 hours, 10 mg ml À1 MWCNTs were disseminated in 5 mg ml À1 SDBS. Then, to make GO/CNT dispersion, 40 mg ml À1 graphene oxide solution was mixed thoroughly with CNTs solution. The RGO-CNT-WO 3 nanocomposite was then synthesized by dissolving 2 g of Na 2 WO 4 $2H 2 O in 30 ml of deionized water and stirring it for 30 minutes with a magnetic stirrer. Then, drop by drop, 3 M HCl was added until the pH reached 1. Then, 3.06 g of oxalic acid and 4 g of (NH 4 ) 2 SO 4 were added aer that. The solution was then diluted with 50 ml of deionized water. Aer that, the CNT solution was gently added using sonication for 45 minutes. The solution was then positioned into a Teon-lined stainless steel autoclave and heated for 20 hours at 180 C. RGO-CNT-WO 3 precipitates were obtained by ltration and washing with acetone and DI water multiple times before being dried for 12 hours in a vacuum oven at 80 C. The nal black product is exhibited in Fig. 1d. The Schematic diagram of the synthesis of RGO-CNT-WO 3 through hydrothermal method has been displayed in Fig. 2.

Structural characterization
The crystal structure was studied through X-ray diffraction (XRD; Rigaku Diffractometer) using Cu Ka radiation with a wavelength of (l ¼ 1.5416 A) and a temperature range of 5 to 60 . Raman Spectroscopy (Jobin Yvon HR800) was also used to do the Raman analysis, which used a He-Ne laser with a wavelength of 632.8 nm. Scanning Electron Microscopy was employed to investigate the morphology of nanocomposites (Nova NanoSEM 430, 10 kV).

Electrochemical characterization and fabrication of electrodes
Under a three-electrode cell conguration in 3 M KOH at ambient temperature, cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), electrochemical impedance spectroscopy (EIS), and cyclic stability tests of composite electrodes were investigated. As working, counter, and reference electrodes, the as-prepared composite electrodes, platinum wire, and Ag/AgCl were employed respectively. On an electrochemical workstation (Gamry Reference 3000 Instrument, USA), all electrochemical properties were recorded. To make the working electrodes, the nickel sponge was cleaned with acetone, 2 M HCl, ethanol, and DI water many times for 15 minutes each. Aer that, it is dried entirely at 90 C for 12 hours. The nickel sponge was sliced into (1 Â 1 cm 2 ) dimensions aer drying. In NMP solution, the electrode active material, polyvinylidene ouride (PVDF), and acetylene black were mixed in 80 : 10 : 10 ratio to produce a homogenous slurry. Finally, this paste was spread onto sponge to make composite electrodes, which were then dried for 8 hours at 90 C. The difference between loaded and unloaded nickel foam was used to compute the loading density of active materials for composite electrodes. The loading density of active materials for all electrodes was 1 mg cm À2 . Using an Ag/AgCl reference electrode, CV experiments were conducted in the 0-0.48 voltage range at 5, 10, 20, 40 and 50 mV s À1 . GCD tests were performed at densities of 2, 4, 6, and 8 A g À1 . EIS study was performed with a 10 mV AC voltage amplitude and a frequency range of 1 Hz to 10 5 Hz. Eqn (1) and (2) are used to calculate specic capacitance (C s ) from CVs and galvanostatic discharging curves respectively; where, i (V) is voltammetric current, m (g) represents the mass of active materials, DV (V) is the potential window, n (mV s À1 ) is the scan rate, I (A) is applied current while Dt (s) is total discharging time. 22,23 The coulombic efficiency of an electrode can be computed by using the following relation while t D and t C are charging and discharging time respectively. 24 3. Results and discussion

Physical characterizations
The crystallinity of WO 3 , RGO-WO 3 , CNT-WO 3 , RGO-CNT-WO 3 materials was studied using X-ray diffraction (XRD, Rigaku diffractometer) with Cu Ka radiation (l ¼ 1.5416 A). Scanning electron microscopy (SEM, Hitachi S4800, operating voltage 10 kV) was used to examine the morphologies of the produced materials. Raman spectrometer (Jobin Yvon HR 800) equipped with He-Ne laser was used to record Raman spectra at an excitation source of 632.8 nm wavelength.

XRD analysis.
To determine the crystalline nature of samples, X-ray diffraction is employed. The range to analyse spectra was 5 to 60 .  [25][26][27] The high crystallinity helps to improve the overall electrochemical performance of synthesized electrodes. 28 A peak observed at 23.5 specied to the successful conversion of graphene oxide into reduced graphene oxide through hydrothermal route. The XRD patterns of composites did not show any peak of GO at 10 , indicating that the GO reduction was done properly throughout the composite preparation. The presence of CNTs is conrmed by the peak located at 26.4 . 29 3.1.2 SEM analysis. The morphological characteristics of WO 3 , RGO-WO 3 , CNT-WO 3 , RGO-CNT-WO 3 were studied by scanning electron microscopy. Fig. 4 shows that WO 3 nanocomposites have uniform 3 dimensional architectures having owerlike shape. In addition, highly magnied images endorse that these architectures are composed of many sheet-like petals and no breakage or collapse is observed in these petals. In RGO/ CNT based tungsten trioxide nanocomposites, these ower like architectures of WO 3 are assembled very well on reduced graphene sheets which are connected to CNTs having strong interfacial contact which ultimately provides the fastest electron transport and hence enhances the performance of electrode. 29 The pores in RGO/CNTs network provide vast channels for ion-transportation and inter-connected sheet works as conduction skeleton for electron transportation. This unique feature also provides enhanced contact area with electrolytic ions which results in path length reduction thus leads to promotion of fast electrons and ion transportation. This will overall improve the electrochemical performance. 30 The corresponding EDS spectra of all nanocomposites, displayed in As depicted in Fig. 5, there are six modes (Raman active) for tungsten trioxide (WO 3 ). A G peak, D peak and 2D bands for RGO-CNTs are located at 1331 cm À1 , 1589 cm À1 and 2650 cm À1 respectively. A D-band referred to defects present in carbon nanostructures whereas scattering of sp 2 carbon atoms results in G-peak. Also, 2D bands are created as a result of dual resonance processes. The peak located at 936.9 cm À1 attributes to W]O bond stretching, whereas stretching vibration of oxygen (O-W-O) is related to the peaks 763.1 cm À1 and 806.2 cm À1 respectively. The bending vibration of (W-O-W) occurs and  results in a peak at 264 cm À1 while peak located at 328 cm À1 correlates to v (W-OH 2 ) vibrations. Additionally, a pair of peaks are found at 84 cm À1 and 270 cm À1 . Also, in addition, two lowintensity peaks referred to D & G bands, representing the presence of RGO-CNTs in CNT-WO 3 , RGO-WO 3 and RGO-CNT-WO 3 nanostructures. 31-34

Electrochemical characterizations
To prepare the working electrodes, the active materials (80 wt%), acetylene black (10 wt%) and PVDF (solvent is NMP) are mixed and pressed on a nickel foam and nally dried in an oven at a temperature of 120 C for 10 hours. The cyclic voltammetry (CV), galvanostatic charge discharge (GCD), cyclic stability and electrochemical impedance spectroscopy (EIS) were employed to study the electrochemical features of asprepared electrodes in a three-electrode cell conguration in 3 M KOH electrolytic solution while this cell conguration contains a Pt wire acting as counter electrode, as-prepared electrodes as working electrode and Ag/AgCl electrode worked as reference electrode. A gold wire is used as current collector. These measurements were taken in a potential range 0-0.48 V at various scan rates. Different current densities (2-8 A g À1 ) were employed to record GCD curves. The EIS spectra was taken for frequency range (1-105 Hz) using 10 mV AC perturbation. Cyclic voltammetry (CV) was employed to inspect stability performance of (RGO-CNT-WO 3 ) hybrid electrode. The CV cycles were run for 5000 cycles at a scan rate of 1000 mV s À1 and two CV curves were recorded at scan rate 5 mV s À1 initially and aer 5000th cycle and then capacitance retention of prepared electrode was calculated.
3.2.1 CV analysis. The super-capacitive behaviour of assynthesized electrodes was studied through CV analysis. Fig. 6 manifests the comparison of CV curves of WO 3 , RGO-WO 3 , CNT-WO 3 and RGO-CNT-WO 3 electrodes at a scan rate of 5 mV s À1 . A couple of redox peaks are traced in all CV curves owing to psudocapacitive behaviour arises due to electrochemical reactions. It has been distinctly seen that RGO-CNT-WO 3 electrode displays greater integrated area in comparison to other electrodes implying the fast interaction among RGO/CNT and tungsten trioxide nanostructures which speed up the electrochemical activity, hence the effective and fast transfer of charges. 35 Eqn (1) was used to compute the specic capacitance of each electrode. Among all the electrodes, RGO-CNT-WO 3 composite owns higher capacitance of 691.38 F g À1 as compared to other electrodes ( Table 1). The higher accessible surface area facilitates faster ion adsorption which leads to efficient transportation of charges and ion intercalation 36 resulting in higher specic capacitance of RGO-CNT-WO 3 . The supercapacitive performance of WO 3 , RGO-WO 3 , CNT-WO 3 , RGO-CNT-WO 3 from 5-50 mV s À1 are displayed in Fig. 7.
As expected, the increase in scan rate resulted in increased current density and integrated area with nearly little change in   shape of CV curves which reects the higher reversibility and stability of all electrodes. Nevertheless, as presented in Fig. 7d, even at higher scan rates of 50 mV s À1 , there is no remarkable change in shapes of CV curves which indicates behaviour close to ideal supercapacitor and high rate performance as compared to other electrodes. The specic capacitance variation with scan rates is depicted in Fig. 8. It can be clearly seen that the increase in scan rate reduces specic capacitance because the redox reactions occur only onto the surface as inner electroactive sites for ion intercalation are not available completely and vice versa.
3.2.2 GCD analysis. Galvanostatic charge-discharge analysis is another reliable method for enquiry of electrochemical performance of all electrodes. The GCD curves of WO 3 , RGO-WO 3 , CNT-WO 3 and RGO-CNT-WO 3 electrodes at 2 A g À1 in 3 M KOH electrolytic solution are shown in Fig. 9. All GCD curves reveal typical triangular discharge plateau which are in good symmetry, exhibiting pseudocapacitive behaviour. These GCD curves also display redox peaks which is in accordance with CV curves. Eqn (2) has been used to calculate specic capacitance of all electrodes and the obtained values are 199.7 F g À1 , 480.6 F g À1 , 533.3 F g À1 , 633.3 F g À1 for WO 3 , RGO-WO 3 , CNT-WO 3 and RGO-CNT-WO 3 respectively at 2 A g À1 . In agreement to CV curve, RGO-CNT-WO 3 has longer discharge time, thus exhibiting higher specic capacitance (C s ) of 633.3 F g À1 in comparison of WO 3 , RGO-WO 3 and CNT-WO 3 electrodes.
Such greater performance of RGO-CNT-WO 3 can be credited to (i) the short ion diffusion path and facilitates rapid electron transport which is produced as a result of sufficient interfacial contact amongst RGO/CNT nanosheets and WO 3 nanostructures (ii) WO 3 nanoowers permit reversible and instantaneous oxidation-reduction reactions to enhance the capacitance (iii) the production of electroactive sites increased due to unique hybrid nanostructures. 37 The RGO-CNT-WO 3 electrode possesses specic capacitances of 633.3, 562.6, 429 & 340.7 F g À1 at 2, 4, 6 and 8 A g À1 respectively [ Table 2]. Distinctly, even at a high current density of 8 A g À1 , the capacitance of the RGO-CNT-WO 3 electrode remains as high as 346.7 F g À1 .
To study the effect of higher current densities on specic capacitances, the GCD curves of each electrode at various current densities were obtained as represented in Fig. 10. It is clear that when the current density increases, the discharging Fig. 8 The variation of specific capacitance with scan rates of WO 3 , RGO-WO 3 , CNT-WO 3 , RGO-CNT-WO 3 electrodes at various scan rates. Fig. 9 Comparison of GCD curves of WO 3 , RGO-WO 3 , CNT-WO 3 , RGO-CNT-WO 3 electrodes at a current density of 2 A g À1 .  time for all electrodes reduces. This is because at greater current densities, surface synergy between electrode and electrolyte is more likely to occur, resulting in a reduction in specic capacitance and a faster rate of discharge. 38,39 Fig. 11 illustrates the range of specic capacitance of RGO-CNT-WO 3 electrodes with various current densities WO 3 , RGO-WO 3 , CNT-WO 3, RGO-CNT-WO 3 electrodes with various current densities.

EIS analysis.
The capacitive and resistive behaviour of WO 3 , RGO-WO 3 , CNT-WO 3 , RGO-CNT-WO 3 electrodes were explored using EIS. Fig. 12 illustrates the impedances of asprepared electrodes in a 3 M KOH electrolytic solution over a frequency range of 1 Hz-100 kHz at 10 mV AC amplitude.
It is noticeable that on the real component i.e. the Z 0 axis, the diameter of a semicircle in high frequency zone is associated to the R ct , indicating greater ion diffusion into electrode pores. In the high frequency band, the Nyquist plot of all electrodes displays no semicircle, indicating optimal super-capacitive behaviour. 29,40 In comparison to other electrodes, the RGO-CNT-WO 3 has a relatively low charge transfer resistance of 5.182 U. A vertical curve larger than 45 in the low-frequency zone suggests considerable super-capacitive activity with low diffusion resistance in the electrodes. The analogous circuit (inset) was used to investigate the produced impedance spectra, and    the results are provided in Table 3, where C PE stands for constant phase element. The RGO/CNT conductive network that governs fast electron transfer channels and WO 3 nanoowers that facilitate electrolyte penetration and reduce ion and electron diffusion routes are responsible for the improved electrochemical performance. 41 3.2.4 Coulombic efficiency. The coulombic efficiencies of all electrodes are calculated using eqn (3) to determine their reversibility of redox processes, and the results are reported in [ Table 4].
It is noticed that the RGO-CNT-WO 3 electrode has the highest coulombic efficiency of 94.3% that is more than 93.3%, 93.1% and 90.6% for WO 3 , RGO-WO 3 , CNT-WO 3 accordingly at a current density of 2 A g À1 . Fig. 13 shows the coulombic efficiency vs. current density, revealing the strong reversibility of the redox processes of the RGO-CNT-WO 3 electrode. Furthermore, at a greater current density of 8 A g À1 , the coulombic efficiency of WO 3 exceeds 100%. At 6 A g À1 , the RGO-WO 3 electrode material achieves a coulombic efficiency of 110 percent. The increased (h) value (>100%) of RGO-WO 3 at 6 A g À1 might be attributable to the breakdown of electrode material, which produces extra charges during the discharging cycle. 42 3.2.5 Cyclic stability. Fig. 14 shows the cyclic performance of the RGO-CNT-WO 3 electrode over 5000 cycles, which is achieved by repeating the CV curves at 1000 mV s À1 between the potential 0-0.48 V. The RGO-CNT-WO 3 electrode has a remarkable capacitance retention of 89.09 percent calculated through CV cycles obtained at 5 mV s À1 before and aer 5000 cycles. These CV curves are shown in the inset of Fig. 14 at 5 mV s À1 for the rst cycle and aer the 5000th cycle.
The improved electro-chemical performance of RGO-CNT-WO 3 can be accredited to tungsten trioxide and CNT/RGO nanostructures, which increase the electrolyte-electrode contact area and hence favour ion transport, resulting in a higher rate capability. 43 These ndings suggest that RGO-CNT-WO 3 is a tremendous candidate for use in well-efficient energy storage devices. The comparison of electrochemical performance of (RGO-WO 3 ), (CNT-WO 3 ), and (RGO-CNT-WO 3 ) with the reported literature was done and it is listed in Table 5. The results manifest that the prepared electrodes have capacitance and cyclic stability comparable to or higher than the others, suggesting the superior electrochemical performance. Also, to the best of our knowledge, RGO-CNT-WO 3 electrode has not reported in the literature yet.

Conclusions
In summary, this study shows a simplistic synthesis of graphene oxide (GO) and tungsten trioxide (WO 3 ) nanostructures, followed by hydrothermal hybridization of this transition metal oxide with carbon materials (graphene, CNTs) to produce binary and ternary nanocomposites. XRD analysis conrms the monoclinic phase and high crystallinity of WO 3 . SEM investigation demonstrates the RGO/CNT network integrated with WO 3 nanoowers in binary and ternary nanocomposites. Many of the vibrational modes of WO 3 and D, G peaks of RGO/CNTs have been conrmed through Raman investigation. According to electrochemical results, the (RGO-CNT-WO 3 ) electrode Fig. 14 Cyclic stability of RGO-CNT-WO 3 composite electrode at 1000 mV s À1 for 5000 cycles. The inset shows the CV curves obtained at 5 mV s À1 before and after 5000 cycles. among all pure and binary nanocomposite electrodes has a superb specic capacitance of 633.3 F g À1 at a current density of 2 A g À1 , a coulombic efficiency of 94.3% at 2 A g À1 , and specic capacitance retention of about 89.09% for 5000 cycles at a scan rate of 1000 mV s À1 . In short, (RGO-CNT-WO 3 ) nanocomposite electrode exhibits superior specic capacitance, reversibility, cyclic stability, coulombic efficiency and low resistances making it suitable for use in supercapacitors. For high-performance supercapacitor applications, this facile methodology also provides an easy way to synthesize novel electrode materials with improved electrochemical properties.

Conflicts of interest
There are no conicts to declare.