Feeding experiments with (–)-[12,12-2H2]rishitin (1-D) in healthy potato tuber tissues indicated that metabolism of (1) into rishitin M-2 (3) proceeded with a stereospecific 1,2-migration of an olefinic hydrogen at C-12 of (1) in contrast with formation of rishitin M-1 (2) by direct oxygenation on C-13 of (1).
A. Murai, Y. Yoshizawa, M. Ikura, N. Katsui and T. Masamune, J. Chem. Soc., Chem. Commun., 1986, 891 DOI: 10.1039/C39860000891
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