Issue 45, 2021

Hypercrosslinking chiral Brønsted acids into porous organic polymers for efficient heterogeneous asymmetric organosynthesis

Abstract

Here, we developed a construction strategy for directly immobilizing the axially chiral phosphoric acid into hypercrosslinked polymers by a one-pot Friedel–Crafts alkylation reaction. The obtained chiral polymers have high porosity, excellent stability and tailorable catalytic centers, and display excellent activity, enantioselectivity and recyclability for asymmetric transfer hydrogenation.

Graphical abstract: Hypercrosslinking chiral Brønsted acids into porous organic polymers for efficient heterogeneous asymmetric organosynthesis

Supplementary files

Article information

Article type
Communication
Submitted
31 Aug 2021
Accepted
04 Nov 2021
First published
04 Nov 2021

J. Mater. Chem. A, 2021,9, 25369-25373

Hypercrosslinking chiral Brønsted acids into porous organic polymers for efficient heterogeneous asymmetric organosynthesis

Y. Zhang, Z. Zhang, S. Ma, J. Jia, H. Xia and X. Liu, J. Mater. Chem. A, 2021, 9, 25369 DOI: 10.1039/D1TA07449K

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