Ba2B7O12F with novel FBB [B7O16F] and deep-ultraviolet cut-off edge

Zhaohong Miao; Yun Yang; Zhonglei Wei; Zhihua Yang; Shilie Pan

doi:10.1039/D0QI00924E

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Ba₂B₇O₁₂F with novel FBB [B₇O₁₆F] and deep-ultraviolet cut-off edge†

Zhaohong Miao,‡^ab Yun Yang,‡^a Zhonglei Wei,^ab Zhihua Yang

^a and Shilie Pan

*^a

Author affiliations

* Corresponding authors

^a CAS Key Laboratory of Functional Materials and Devices for Special Environments; Xinjiang Technical Institute of Physics & Chemistry, CAS; Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China
E-mail: slpan@ms.xjb.ac.cn

^b Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

A new member in the barium fluorooxoborate family, namely Ba₂B₇O₁₂F, was obtained by the high-temperature solution method in an open system under ambient pressure. The structure features a new fundamental building block [B₇O₁₆F], which interconnects with each other to form the anionic framework [B₇O₁₂F]_∞ with two different caves in which the cations reside. The experiment result indicates that Ba₂B₇O₁₂F possesses a deep-ultraviolet cut-off edge below 180 nm.

This article is part of the themed collection: 2020 Inorganic Chemistry Frontiers HOT articles

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D0QI00924E
Article type: Research Article
Submitted: 03 Aug 2020
Accepted: 29 Oct 2020
First published: 30 Oct 2020

Download Citation

Inorg. Chem. Front., 2021,8, 339-343

Permissions

Request permissions

Ba₂B₇O₁₂F with novel FBB [B₇O₁₆F] and deep-ultraviolet cut-off edge

Z. Miao, Y. Yang, Z. Wei, Z. Yang and S. Pan, Inorg. Chem. Front., 2021, 8, 339 DOI: 10.1039/D0QI00924E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Inorganic Chemistry Frontiers