SCHEDULED MAINTENANCE
Using experimental and computational approaches to probe an unusual carbon–carbon bond cleavage observed in the synthesis of benzimidazole N-oxides†
Fabrizio
Politano, 
ab
Arturo León
Sandoval,
a
Jorge G.
Uranga,
b
Elba I.
Buján
b
and
Nicholas E.
Leadbeater
*a
ab
Arturo León
Sandoval,
a
Jorge G.
Uranga,
b
Elba I.
Buján
b
and
Nicholas E.
Leadbeater
*a
Abstract
Experimental and computational studies have been performed in order to investigate an unusual carbon–carbon bond cleavage that occurs in the preparation of certain benzimidazole N-oxides from anilines. The key factor determining the outcome of the reaction was found to be the substituents on the amine functionality of the aniline.
- This article is part of the themed collection: Mechanistic, computational & physical organic chemistry in OBC
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