Words in supramolecular chemistry: the ineffable advances of polyiodide chemistry

Abstract

Polyiodide chemistry has a rich history deeply intertwined with the development of supramolecular chemistry. Technological and theoretical interest in polyiodides has not diminished in the last decade, quite the contrary; yet the advances this perspective intends to cover are muddled by the involution of supramolecular vocabulary, preventing their unbiased discussion. Herein we discuss the pressing necessity of ordering the current babel of novel – and less so – supramolecular terms. Shared decisions at the community level might be required to shape the field into a harmonious body of knowledge, dominated by concepts rather than words. Secondary, σ-hole and halogen bonding schools of thought are all addressed here, together with their respective impact on the field. Then, on the basis of a shared vocabulary, a discussion of polyiodide chemistry is presented, starting with a revisited view of triiodide. The contemporary fields of supramolecular caging and polyiodide networks are then discussed, with emphasis on how the terms we choose to use deeply affect scientific progress.