A high-Tc organic-ionic phase transition crystal obtained from a trivalent cation

Yu-Hua Liu; Jun-Chao Liu; Hang Peng; Xue-Qin Huang; Wei-Qiang Liao; Zhong-Xia Wang

doi:10.1039/D0CE01654C

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A high-T_c organic-ionic phase transition crystal obtained from a trivalent cation†

Yu-Hua Liu,‡^a Jun-Chao Liu,‡^a Hang Peng,‡^a Xue-Qin Huang,^a Wei-Qiang Liao

*^a and Zhong-Xia Wang

*^a

Author affiliations

* Corresponding authors

^a Ordered Matter Science Research Center, Nanchang University, Nanchang 330031, People's Republic of China
E-mail: liaowq@ncu.edu.cn, zhongxiawang@ncu.edu.cn

Abstract

Previously, organic-ionic crystal phase transition materials have mainly focused on mono- or divalent organic amine cations, while higher valent amine cations have rarely been introduced. Here, we have selected a ring-shaped trivalent organic amine, triethylenetriamine, in order to construct a high-T_c phase transition material, triethylenetriammonium trichloride ([HTETA]³⁺ 3[Cl]⁻).

This article is part of the themed collection: Crystal Growth

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Article information

DOI: https://doi.org/10.1039/D0CE01654C
Article type: Communication
Submitted: 15 Nov 2020
Accepted: 26 Nov 2020
First published: 26 Nov 2020

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CrystEngComm, 2021,23, 264-267

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A high-T_c organic-ionic phase transition crystal obtained from a trivalent cation

Y. Liu, J. Liu, H. Peng, X. Huang, W. Liao and Z. Wang, CrystEngComm, 2021, 23, 264 DOI: 10.1039/D0CE01654C

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