A porous supramolecular ionic solid

Nathan Jackson; Irma Rocio Vazquez; Ying-Pin Chen; Yu-Sheng Chen; Wen-Yang Gao

doi:10.1039/D1CC02806E

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A porous supramolecular ionic solid†

Nathan Jackson,^b Irma Rocio Vazquez,^b Ying-Pin Chen,^c Yu-Sheng Chen^c and Wen-Yang Gao

*^a

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* Corresponding authors

^a Department of Chemistry, New Mexico Institute of Mining and Technology, Socorro, New Mexico 87801, USA
E-mail: wenyang.gao@nmt.edu

^b Department of Mechanical Engineering, University of New Mexico, Albuquerque, New Mexico, 87106, USA

^c NSF's ChemMatCARS, The University of Chicago, Lemont, Illinois, 60439, USA

Abstract

We report a synthetic strategy to integrate discrete coordination cages into extended porous materials by decorating opposite charges on the singular cage, which offers multidirectional electrostatic forces among cages and leads to a porous supramolecular ionic solid. The resulting material is non-centrosymmetric and affords a piezoelectric coefficient of 8.19 pC N⁻¹, higher than that of the wurtzite ZnO.

This article is part of the themed collection: ChemComm Milestones – First Independent Articles

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DOI: https://doi.org/10.1039/D1CC02806E
Article type: Communication
Submitted: 27 May 2021
Accepted: 24 Jun 2021
First published: 24 Jun 2021

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Chem. Commun., 2021,57, 7248-7251

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A porous supramolecular ionic solid

N. Jackson, I. R. Vazquez, Y. Chen, Y. Chen and W. Gao, Chem. Commun., 2021, 57, 7248 DOI: 10.1039/D1CC02806E

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Chemical Communications

A porous supramolecular ionic solid†

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A porous supramolecular ionic solid

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