Issue 47, 2021
From the journal:

Chemical Communications

BINOLated aminostyryl BODIPYs: a workable organic molecular platform for NIR circularly polarized luminescence†

Josué Jiménez,a   Carolina Díaz-Norambuena,b   Sergio Serrano,a   Shing Cho Ma,c   Florencio Moreno, ORCID logo a   Beatriz L. Maroto,a   Jorge Bañuelos, ORCID logo b   Gilles Muller ORCID logo c  and  Santiago de la Moya ORCID logo *a  

* Corresponding authors

a Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Ciudad Universitaria s/n, Madrid, Spain
E-mail: santmoya@ucm.es

b Departamento de Química Física, Universidad del País Vasco-EHU, Apartado 644, Bilbao, Spain

c Department of Chemistry, San José State University, San José, CA 95192-0101, USA

Abstract

The accessible at-boron-BINOLated 3,5-bis(4-aminostyryl)ated BODIPY scaffold is highlighted as a workable platform for developing enantiopure small organic molecules exhibiting CPL in the NIR region, even in water solution, the latter being key for CPL-based bioapplications. Synthetic simplicity, noticeable chiroptical efficiency in the NIR and the possibility to access water-soluble emitters pave the way for advancing CPL tools based on organic emitters and NIR radiation.

Graphical abstract: BINOLated aminostyryl BODIPYs: a workable organic molecular platform for NIR circularly polarized luminescence

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Article information

DOI
https://doi.org/10.1039/D1CC01255J
Article type
Communication
Submitted
08 Mar 2021
Accepted
10 May 2021
First published
11 May 2021

Chem. Commun., 2021,57, 5750-5753

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BINOLated aminostyryl BODIPYs: a workable organic molecular platform for NIR circularly polarized luminescence

J. Jiménez, C. Díaz-Norambuena, S. Serrano, S. C. Ma, F. Moreno, B. L. Maroto, J. Bañuelos, G. Muller and S. de la Moya, Chem. Commun., 2021, 57, 5750 DOI: 10.1039/D1CC01255J

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