Issue 32, 2021

Zero-valent metals in metal–organic frameworks: fac-M(CO)3(pyrazine)3/2

Abstract

We report the synthesis of pyrazine-pillared metal–organic frameworks (MOFs) generated through ligand substitution of the Group 6 metal hexacarbonyls. The obtained frameworks exhibit hexagonal pore channels with CO-plastered porewalls. This series constitutes the first crystallographically characterized examples of Cr(0), Mo(0), and W(0)-based MOFs and suggests the exploration of homoleptic metal carbonyls as starting materials to generate polymeric materials with low-valent metal nodes.

Graphical abstract: Zero-valent metals in metal–organic frameworks: fac-M(CO)3(pyrazine)3/2

Supplementary files

Article information

Article type
Communication
Submitted
15 Feb 2021
Accepted
25 Mar 2021
First published
25 Mar 2021

Chem. Commun., 2021,57, 3861-3864

Zero-valent metals in metal–organic frameworks: fac-M(CO)3(pyrazine)3/2

L. Voigt, R. Wugt Larsen, M. Kubus and K. S. Pedersen, Chem. Commun., 2021, 57, 3861 DOI: 10.1039/D1CC00864A

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