Issue 24, 2021

Unexpected aliovalent cation substitution between two NLO materials LiBa3Bi6(SeO3)7F11 and Ba3Bi6.5(SeO3)7F10.5O0.5

Abstract

One new combination, alkali-metal and alkaline earth-metal selenite fluoride, LiBa3Bi6(SeO3)7F11 (LBBSF) and its analogue Ba3Bi6.5(SeO3)7F10.5O0.5 (BBSF) were reported here for the first time. Unusual aliovalent cation substitution between them affected the layer thickness and made the bond strains of [SeO3] enhanced, thereby inducing greater distortions and affecting the SHG efficiencies. This work may provide thoughts for exploring new NLO materials.

Graphical abstract: Unexpected aliovalent cation substitution between two NLO materials LiBa3Bi6(SeO3)7F11 and Ba3Bi6.5(SeO3)7F10.5O0.5

Supplementary files

Article information

Article type
Communication
Submitted
20 Jan 2021
Accepted
22 Feb 2021
First published
27 Feb 2021

Chem. Commun., 2021,57, 2982-2985

Unexpected aliovalent cation substitution between two NLO materials LiBa3Bi6(SeO3)7F11 and Ba3Bi6.5(SeO3)7F10.5O0.5

S. Shi, C. Lin, D. Zhao, M. Luo, L. Cao, G. Peng and N. Ye, Chem. Commun., 2021, 57, 2982 DOI: 10.1039/D1CC00346A

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