Issue 19, 2021

Thermochromism and piezochromism of an atomically precise high-nuclearity silver sulfide nanocluster

Abstract

A novel high-nuclearity silver sulfide nanocluster [Ag50S7(SC6H4F)36(dppp)6]·4DMI, (hereafter abbreviated as 1⋅4DMI) was synthesised. Solvent-free crystals of 1 displayed a completely reversible narrowing and broadening of the optical band gap that was accompanied by visual thermochromism and piezochromism changeovers, when stimulated by varying temperatures between 113 and 413 K or by changing the pressure from 1 atm to 7.5 GPa.

Graphical abstract: Thermochromism and piezochromism of an atomically precise high-nuclearity silver sulfide nanocluster

Supplementary files

Article information

Article type
Communication
Submitted
26 Oct 2020
Accepted
26 Jan 2021
First published
27 Jan 2021

Chem. Commun., 2021,57, 2372-2375

Thermochromism and piezochromism of an atomically precise high-nuclearity silver sulfide nanocluster

Q. Sun, Q. Li, H. Li, M. Zhang, M. Sun, S. Li, Z. Quan and S. Zang, Chem. Commun., 2021, 57, 2372 DOI: 10.1039/D0CC07085H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements