Ferrocene-derived Fe-metalated porous organic polymer for the core planarity-triggered detoxification of chemical warfare agents†
Ratul
Paul, 
‡ab
Chitra
Sarkar,
‡ab
Manjari
Jain,
‡c
Shaojun
Xu,
de
Kashmiri
Borah,
f
Duy Quang
Dao,
g
Saswata
Bhattacharya
*c
and
John
Mondal
*ab
‡ab
Chitra
Sarkar,
‡ab
Manjari
Jain,
‡c
Shaojun
Xu,
de
Kashmiri
Borah,
f
Duy Quang
Dao,
g
Saswata
Bhattacharya
*c
and
John
Mondal
*ab
Abstract
Herein, we demonstrate the successful construction of two Fe-metalated porous organic polymers having planar (Fe-Tt-POP) and non-planar (Fe-Rb-POP) geometry via the ternary copolymerization strategy for the catalytic oxidative decontamination of different sulfur-based mustard gas simulants (HD). Fe-Tt-POP exhibits superior catalytic performance for the oxidation of thioanisole (TA) in comparison with Fe-Rb-POP. Interestingly, this activity difference can be further explored by in situ operando DRIFTS and DFT computational studies.
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