A new family of boat-shaped Ln8 clusters exhibiting the magnetocaloric effect and slow magnetic relaxation

Abstract

Designing and synthesizing lanthanide clusters have always been a research hotspot. Herein, three lanthanide clusters with the formula [Ln₈(IN)₁₄(μ₃-OH)₈(μ₂-OH)₂(H₂O)₈]·xH₂O (Ln = 1-Gd and x = 11; Ln = 2-Dy and x = 8; Ln = 3-Eu and x = 8) have been isolated in the presence of isonicotinic acid under solvothermal conditions. Structural analysis indicates that those three compounds are isostructural, featuring boat-shaped {Ln₈} metal frameworks. Magnetic measurements reveal that 1-Gd exhibits a larger MCE with the maximum −ΔS_m value of 31.77 J kg⁻¹ K⁻¹ at 2 K for ΔH = 7 T, while 2-Dy displays slow magnetization relaxation. Besides, the photoluminescence properties of 3-Eu were investigated.