Issue 1, 2020
From the journal:

New Journal of Chemistry

An aminotetracyanocyclopentadienide system: light-induced formation of a thermally stable cyclopentadienyl radical†

Patrick R. Nimax,a   Florian Zoller,a   Tobias Blockhaus,a   Teresa Küblböck,a   Dina Fattakhova-Rohlfingb  and  Karlheinz Sünkel ORCID logo *a  

* Corresponding authors

a Department Chemistry, Ludwig-Maximilians-University Munich, Butenandtstr. 9-11, 81377 Munich, Germany
E-mail: suenk@cup.uni-muenchen.de

b Electrochemical Storage Department, Institut für Energie- und Klimaforschung: Werkstoffsynthese und Herstellungsverfahren (IEK-1), Forschungszentrum Jülich GmbH Wilhelm-Johnen-Straße, 52425 Juelich, Germany

Abstract

Crystals of the aminotetracyanocyclopentadienyl radical were obtained from the reaction of CaCl2 with Ag[C5(CN)4(NH2)] and recrystallization in MeOH, performed in sunlight. The radical was characterized by X-ray diffraction, EPR and UV Vis spectroscopy as well as by cyclovoltammetry and DFT calculations.

Graphical abstract: An aminotetracyanocyclopentadienide system: light-induced formation of a thermally stable cyclopentadienyl radical

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Article information

DOI
https://doi.org/10.1039/C9NJ04354C
Article type
Paper
Submitted
22 Aug 2019
Accepted
16 Nov 2019
First published
18 Nov 2019

New J. Chem., 2020,44, 72-78

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An aminotetracyanocyclopentadienide system: light-induced formation of a thermally stable cyclopentadienyl radical

P. R. Nimax, F. Zoller, T. Blockhaus, T. Küblböck, D. Fattakhova-Rohlfing and K. Sünkel, New J. Chem., 2020, 44, 72 DOI: 10.1039/C9NJ04354C

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